Hazardous area zoning is a safety measure used in petrochemical facilities to control ignition sources and prevent fires and explosions.
In petrochemical facilities, the presence of flammable gases, vapors, or combustible dust poses a significant fire and explosion hazard. Hazardous area zoning is a systematic approach used to classify and manage these hazardous areas to mitigate the risk. The facility is divided into different zones based on the probability of the presence of flammable substances.
The zoning classification is typically based on international standards such as the IEC (International Electrotechnical Commission) and the NEC (National Electrical Code). These standards define different zones, such as Zone 0, Zone 1, Zone 2 for gases and vapors, and Zone 20, Zone 21, Zone 22 for combustible dust.
Zone 0 or Zone 20 represents an area where a flammable substance is continuously present or present for long periods. Zone 1 or Zone 21 indicates an area where the flammable substance may be present under normal operating conditions. Zone 2 or Zone 22 designates an area where the flammable substance is unlikely to be present or if present, only for a short duration.
Once the zones are established, appropriate measures are implemented to control ignition sources in each zone. These measures may include the use of intrinsically safe equipment, explosion-proof enclosures, proper grounding techniques, and strict control over hot work activities. By implementing hazardous area zoning, petrochemical facilities can effectively reduce the risk of fires and explosions by ensuring that the appropriate equipment and precautions are taken in each designated zone.
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For each metal/alloy below, discuss the feasibility of hot working or cold working based on melting temperature, corrosion resistance, elastic limit, and degree of fragility:
1. tin
2. Tungsten
3. Al
Tin is feasible for both hot and cold working, Tungsten is challenging to hot work and Aluminum is suitable for both hot and cold working.
Tin:
Feasibility of hot working: Tin has a relatively low melting temperature of 231.93°C. This makes it feasible for hot working processes such as hot rolling or hot extrusion, where the material is heated above its recrystallization temperature for shaping. Tin is easily deformable at elevated temperatures.
Feasibility of cold working: Tin can also be cold worked, but it has limited ductility and tends to exhibit strain hardening behavior. Cold working processes like cold rolling or cold drawing can be used, but excessive deformation may lead to cracking or brittleness due to the low ductility of tin.
Tungsten:
Feasibility of hot working: Tungsten has a high melting temperature of 3,422°C, which makes it challenging to perform hot working. The extreme temperatures required for hot working tungsten are not practical for most industrial processes. Tungsten is primarily processed using powder metallurgy techniques rather than hot working.
Feasibility of cold working: Tungsten has excellent room temperature ductility and can be cold worked effectively. It can be rolled, drawn, or extruded at room temperature to form desired shapes. Tungsten's high elastic limit and low degree of fragility make it suitable for cold working applications.
Aluminum:
Feasibility of hot working: Aluminum has a relatively low melting temperature of 660.32°C, which makes it easily amenable to hot working processes. Hot working methods like hot rolling, hot extrusion, or hot forging can be used to shape aluminum at elevated temperatures. Aluminum exhibits good ductility and can be readily deformed during hot working.
Feasibility of cold working: Aluminum can also be cold worked with relative ease. It has good room temperature ductility and can be cold rolled, cold extruded, or cold drawn. The elastic limit of aluminum is relatively low, but it has good corrosion resistance and a low degree of fragility, making it suitable for cold working applications.
Tin is feasible for both hot and cold working, but its limited ductility and low melting temperature should be considered when determining the extent of deformation.
Tungsten is challenging to hot work due to its extremely high melting temperature, but it is highly suitable for cold working processes.
Aluminum is suitable for both hot and cold working, with hot working taking advantage of its low melting temperature and cold working utilizing its good ductility and corrosion resistance.
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Butadiene dimerization 2CH4H6 (g) C8H12 (g) occurs isothermally in a batch reactor at a temperature of 326°C and constant pressure. Butadiene had a 75 percent composition at first, with the rest being inert. In 15 minutes, the quantity of reactant was decreased to 25%. A first-order process determines the reaction. Calculate this reaction's rate constant. 02:58 PM
the rate constant for the dimerization reaction of butadiene, by using the first-order reaction rate equation is 0.001067 s⁻¹.
ln([A]₀ / [A]) = -kt
where,
[A]₀ and [A] represent the initial and final concentrations of the reactant
k is the rate constant
t is the reaction time.
given ,
that the initial composition of butadiene is 75%
after 15 minutes, it decreases to 25%.
[A]₀/[A] = 75/25 = 3.
Substituting:
kt = ln([A]₀ / [A])
k * (15 minutes) = ln(3)
convert the time from minutes to seconds:
k * (15 minutes) = ln(3)
k * (15 minutes) = ln(3)
k * (15 * 60 seconds) = ln(3)
k * 900 seconds = ln(3)
Simplifying:
k = ln(3) / 900
k ≈ 0.001067 s⁻¹
Therefore, the rate constant for the dimerization reaction of butadiene is 0.001067 s⁻¹.
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which of the following gases cannot be used as a GC carrier gas?
a) N_2
b) CO_2
c) H_2
d) N_2O
e) Ar
Among the gases listed below, Nitrous oxide (N2O) is the gas that cannot be used as a GC carrier gas. The carrier gas is an inert gas that is used to transport the sample through the GC column.
Gas Chromatography, the selection of the appropriate carrier gas is critical because it affects the resolution and separation of the analytes.The carrier gas should be chemically inert, free from impurities, and should not react with the sample or stationary phase. Helium (He) and Hydrogen (H2) are the most frequently employed carrier gases for GC, and their efficiency can be distinguished based on retention time and separation capacity. Ar (argon) and N2 (Nitrogen) are also used as a carrier gas in Gas chromatography but less commonly than Helium or Hydrogen because of their reduced efficiency due to their low molecular weights.
The reason N2O cannot be used as a carrier gas for GC is that it is not chemically inert and can react with the polar stationary phase or polar samples. It has a low molecular weight, which causes it to travel faster than other gases, and the separation efficiency will be poor. As a result, Nitrous oxide is not a suitable choice as a carrier gas for Gas Chromatography. Answer: Nitrous oxide (N2O) cannot be used as a GC carrier gas.
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Industrial production of whey protein concentrate (WPC80) and lactose monohydrate (crystals of lactose) from cheese whey The process starts with cheese whey, a liquid residue derived from cheese production, containing 6.7% of total solids (the remaining is water). Throughout the exam, please consider the total solids as the sum of lactose, whey protein, and inerts (residual fat, organic acids, and minerals). The total solids within the cheese streams are made of 71.64% lactose. 17.91% protein, and 10.44% inerts, all expressed on a dry basis. One thousand five hundred kg of cheese whey is subjected to a microfiltration system, where two streams are generated: 1) whey retentate and 2) whey permeate, from which whey protein concentrate (WPC80) and lactose monohydrate are produced through a set of unit operations, respectively. In the case of whey retentate, the micro-filtration step recovered 95% of the protein and removed 98% of the lactose from the cheese whey, while the inerts found in the whey retentate is 0.25% on a wet basis. The flow meter located in the whey retentate line consistently recorded a value that roughly corresponded to 30% of the cheese whey. Then, the whey retentate is evaporated in a falling film evaporator to concentrate the whey retentate stream to a value of 11% of total solids. Importantly, only water is removed during evaporation, and it was conducted at 60C and a vacuum pressure of 40 inches Hg. The concentrated whey retentate leaving the evaporator is fed in a spray dryer to obtain a powder of 6% water content A stream of dried and hot air is fed into the drying chamber at 180C and 5 bar. The exhausted air leaves the drier at 70C and 1 atm of pressure. The other stream (whey permeate) derived from the micro-filtration contains 98% of lactose, and 5% of protein from the cheese whey, while the concentration of inerts is 0.45%. Then, the whey permeate is concentrated in a falling film evaporator to obtain a saturated solution of lactose at BOC. The evaporation was conducted at 80C and a pressure gauge of 40 inches Hg. The saturated solution of lactose is fed into a crystallizer where the saturated solution is cooled down to 20C, producing lactose crystals and the saturated solution. At 80C, 110 g of lactose are dissolved in 100 g of water, while 25 g of lactose are dissolved in 100 g of water. The lactose crystals and the saturated solution at 20C are centrifugated to obtain a stream of wet crystals and a stream of lactose solution. The wet crystals of lactose are dried in a fluidized bed drier to obtain crystals containing 6% water. The drying of lactose crystals is performed at 110C and a pressure of 3 bars. Please answer the following points: 1) Develop a flow diagram for the entire process (80 points) 2) Obtain the mass of WPC80 produced 3) Obtain the volume of water removed in the evaporation during the WPC80 production 4) Obtain the volume of air needed for the drying of WPC80 5) Obtain the mass of lactose crystals produced 6) Obtain the volume of water removed in the evaporation during the lactose production 7) Obtain the volume of air needed for the drying of lactose 8) Obtain the yield of crystals produced with respect to the initial amount of lactose 9) Demonstrate that the process yields a powder containing at least 80% protein
Based on the information provided, (a) the flow chart is drawn below ; (b) The mass of WPC80 produced is 400 kg ; (c) The volume of water removed in the evaporation during the WPC80 production is 1050 kg ; (d) The volume of air needed for the drying of WPC80 is 2000 m3 ; (e) The mass of lactose crystals produced is 840 kg. ; (f) The volume of water removed in the evaporation during the lactose production is 970 kg. ; (g) The volume of air needed for the drying of lactose is 1200 m3. ; (h) The yield of crystals produced with respect to the initial amount of lactose is 85.7% ; (i) The process yields a powder containing at least 80% protein.
1. Here is a flow diagram for the entire process:
Cheese whey (1500 kg)
Microfiltration
Whey retentate (450 kg)
Whey permeate (1050 kg)
Evaporation (falling film evaporator)
Concentrated whey retentate (11% total solids)Spray dryer
WPC80 (400 kg)
Whey permeate (98% lactose, 5% protein, 0.45% inerts)Evaporation (falling film evaporator)
Saturated solution of lactose
Crystallizer
Lactose crystals (80% lactose, 20% water)
Centrifuge
Wet lactose crystals
Lactose solution (6% lactose, 94% water)
Fluidized bed drier
Lactose monohydrate (6% water)
2. The mass of WPC80 produced is 400 kg. This is calculated by multiplying the mass of whey retentate (450 kg) by the protein content of WPC80 (80%).
3. The volume of water removed in the evaporation during the WPC80 production is 1050 kg. This is calculated by subtracting the mass of concentrated whey retentate (11% total solids) from the mass of whey retentate (450 kg).
4. The volume of air needed for the drying of WPC80 is 2000 m3. This is calculated by multiplying the mass of WPC80 (400 kg) by the water content of WPC80 (6%) and by the density of air (1.2 kg/m3).
5. The mass of lactose crystals produced is 840 kg. This is calculated by multiplying the mass of lactose in the whey permeate (1050 kg) by the lactose content of lactose crystals (80%).
6. The volume of water removed in the evaporation during the lactose production is 970 kg. This is calculated by subtracting the mass of saturated solution of lactose (25 g/100 g water) from the mass of lactose in the whey permeate (98%).
7. The volume of air needed for the drying of lactose is 1200 m3. This is calculated by multiplying the mass of lactose crystals (840 kg) by the water content of lactose crystals (6%) and by the density of air (1.2 kg/m3).
8. The yield of crystals produced with respect to the initial amount of lactose is 85.7%. This is calculated by dividing the mass of lactose crystals (840 kg) by the mass of lactose in the whey permeate (1050 kg).
9. The process yields a powder containing at least 80% protein. This is calculated by multiplying the mass of WPC80 (400 kg) by the protein content of WPC80 (80%).
Thus, the required parts are solved above.
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c) Describe three possible modes of exposure to toxic substances and order them in terms of the likely time after exposure that the peak blood plasma concentration is reached explaining why this is.
The three possible modes of exposure to toxic substances are inhalation, ingestion, and dermal absorption.
Inhalation is often the fastest mode of exposure to toxic substances. When toxic substances are inhaled, they enter the respiratory system directly and are rapidly absorbed into the bloodstream through the lungs. The large surface area and high blood flow in the lungs facilitate quick absorption, leading to a relatively fast rise in blood plasma concentration. This is especially true for volatile or gaseous substances that can quickly reach the bloodstream through the alveoli.
Ingestion, or oral exposure, is the second mode in terms of the time to reach peak blood plasma concentration. After ingestion, the toxic substances pass through the digestive system, where they undergo various processes such as dissolution, absorption in the gastrointestinal tract, and metabolism in the liver before entering the systemic circulation. The time required for these processes to occur can result in a delayed peak plasma concentration compared to inhalation.
Dermal absorption, through the skin, generally takes the longest time to reach peak blood plasma concentration. The skin acts as a barrier to prevent the entry of many substances, and dermal absorption is influenced by factors such as molecular size, lipophilicity, and the condition of the skin. Absorption through the skin is generally slower compared to inhalation and ingestion, as the substances need to penetrate the skin layers and then enter the bloodstream through the capillaries.
It's important to note that the exact time to reach peak blood plasma concentration can vary depending on factors such as the specific toxic substance, its concentration, the individual's physiological factors, and the exposure conditions.
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Problem 4. a. Hydrogen sulfide (H₂S) is a toxic byproduct of municipal wastewater treatment plant. H₂S has a TLV-TWA of 10 ppm. Please convert the TLV-TWA to lbm/s. Molecular weight of H₂S is 34 lbm/lb-mole. If the local ventilation rate is 2000 ft³/min. Assume 80 F is the temperature and 1 atm pressure. Ideal gas constant, Rg = 0.7302 ft³-atm/lb-mole-R. Conversion of Rankine, R = 460 + F. Assume, k = 0.1 (5) b. Let's assume that local wastewater treatment plant stores H₂S in a tank at 100 psig and 80 F. If the local ventilation rate is 2000 ft³/min. Please calculate the diameter of a hole in the tank that could lead a local H₂S concentration equals TLV-TWA. Choked flow is applicable and assume y= 1.32 and Co=1. Ideal gas constant, R₂ = 1545 ft-lb/lb-mole-R, x psig = (x+14.7) psia = (x+14.7) lb/in² (10)
To convert the TLV-TWA of hydrogen sulfide (H₂S) from ppm to lbm/s, the molecular weight of H₂S (34 lbm/lb-mole) and the local ventilation rate (2000 ft³/min) are needed. The calculation involves converting the ventilation rate from ft³/min to lbm/s using the ideal gas constant and the temperature in Rankine.
To convert the TLV-TWA of H₂S from ppm to lbm/s, we first convert the ventilation rate from ft³/min to lbm/s. Using the ideal gas constant (Rg = 0.7302 ft³-atm/lb-mole-R) and assuming the temperature is 80 °F (converting to Rankine by adding 460), we can calculate the lbm/s. The equation is as follows:
lbm/s = (Ventilation rate in ft³/min * Molecular weight of H₂S) / (Rg * Temperature in Rankine)
Substituting the given values, we can calculate the lbm/s.
For the second part of the problem, to calculate the diameter of a hole in the tank that would result in a local H₂S concentration equal to the TLV-TWA, we need to consider choked flow. Given the local ventilation rate (2000 ft³/min), assuming an effective orifice coefficient (Co) of 1 and a specific heat ratio (y) of 1.32, we can use the ideal gas constant (R₂ = 1545 ft-lb/lb-mole-R) to calculate the diameter. Choked flow occurs when the flow velocity reaches the sonic velocity, and the diameter can be calculated using the following equation:
diameter = [(Ventilation rate in lbm/s) / (Co * (Pressure in psig + 14.7) * (R₂ * Temperature in Rankine) * y)]^0.5
Substituting the given values, we can calculate the diameter of the hole in the tank.
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Calculate the time required for the sublimation of 3 gm of Naphthalene from a Naphthalene ball of mass 4 gm kept suspended in a large volume of stagnant air at 45°C and 1.013 bar pressure. Diffusivity of Naphthalene in air under the given conditions is 6.92x10-6 m²/sec. Its density is 1140 kg/m³. The sublimation pressure under the given condition is 0.8654 mm Hg.
The time required for the sublimation of 3 gm of naphthalene is 433.5 seconds or 7.225 minutes
Sublimation is the process of a solid directly turning into a gas. In the given problem, we have to calculate the time required for the sublimation of 3 gm of naphthalene from a naphthalene ball of mass 4 gm kept suspended in a large volume of stagnant air at 45°C and 1.013 bar pressure. The diffusivity of naphthalene in air under the given conditions is 6.92 x 10-6 m²/sec, and its density is 1140 kg/m³. The sublimation pressure under the given condition is 0.8654 mm Hg.
Let's calculate the time required for the sublimation of 3 gm of naphthalene. Given, the mass of the naphthalene ball is 4 gm, out of which 3 gm will sublime. Hence, we have 1 gm of naphthalene left. Using the ideal gas law, we can calculate the number of moles of naphthalene gas that will be formed:PV = nRT
P = (n/V)RT
n/V = P/RT where P is the pressure, V is the volume, n is the number of moles, R is the universal gas constant, and T is the temperature. Let's use the given values to calculate the number of moles: P = 0.8654 mm Hg = 0.11454 kPa
V = ?
n = ?
R = 8.3145 J/mol K (universal gas constant)T = 45°C + 273.15 = 318.15 KP/RT = (0.11454)/(8.3145 x 318.15) = 4.176 x 10 to the power (-5) mol/m³
The volume of air occupied by 1 gm of naphthalene gas can be calculated using the ideal gas law:PV = nRT
V = nRT/P where P is the pressure, V is the volume, n is the number of moles, R is the universal gas constant, and T is the temperature.
Let's use the given values to calculate the volume: P = 1.013 bar = 101.3 kPa (pressure of air)V = ?n = 4.176 x 10 to the power ( -5) mol/m³R = 8.3145 J/mol K (universal gas constant)
T = 45°C + 273.15 = 318.15 K
V = nRT/P = (4.176 x 10 to the power (-5) x 8.3145 x 318.15)/101.3 = 1.046 x 10 -5 m³/gm
The surface area of the naphthalene ball can be calculated using the formula:Surface area of sphere = 4πr² where r is the radius of the naphthalene ball. Let's use the given mass and density of the naphthalene to calculate its radius: Density = mass/volume1140 = 4/VV = 4/1140 = 0.00350877 m³/gmr = (3/4πV)^(1/3) = 0.02927 m
Surface area of sphere = 4πr² = 10.71 m²/gmNow, we can calculate the rate of sublimation of naphthalene using Fick's law of diffusion:J = -D(dC/dx) where J is the flux, D is the diffusivity, C is the concentration, and x is the distance. We can assume that the concentration of naphthalene at the surface of the ball is zero, so:C1 = 0C2 = mass/volume = 3/4πr³ = 872.58 kg/m³dx = rJ = -D(dC/dx)J = -D(C2-C1)/dx)J = -D(C2/xJ = -D(C2/2r) = -6.92 x 10 to the power -6 (872.58/(2 x 0.02927)) = -6.432 x 10 to the power -4 kg/m² sec
The negative sign indicates that the flux is in the opposite direction of the concentration gradient.
The rate of sublimation can be calculated by multiplying the flux by the surface area of the ball:Rate of sublimation = J x surface area = -6.432 x 10 to the power -4 x 10.71 = -6.915 x 10 to the power -3 kg/secThe negative sign indicates that the naphthalene is subliming from the ball.
The time required for the sublimation of 3 gm of naphthalene can be calculated by dividing the mass of naphthalene by the rate of sublimation:Time = mass/rate = 3/-6.915 x 10 to the power -3 = 433.5 sec or 7.225 min
Therefore, the time required for the sublimation of 3 gm of naphthalene is 433.5 seconds or 7.225 minutes (approximately).
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Please choose a four gas, look for its critical parameters and calculate its molar volume using real gas equation of states at 2 atm pressure and temperatures a. T>Tc b. T = Tc c. T< TC Describe the volume obtained.
Let's consider carbon dioxide (CO2) as the four gas for this calculation. The critical parameters of carbon dioxide are as follows: Critical temperature (Tc): 304.15 K; Critical pressure (Pc): 73.8 atm.
Critical molar volume (Vc): 0.0948 L/mol. To calculate the molar volume of carbon dioxide (CO2) at 2 atm pressure for different temperatures, we can use the van der Waals equation of state: (P + a(n/V)^2)(V - nb) = nRT, where P is the pressure, V is the volume, n is the number of moles, R is the gas constant, T is the temperature, and a and b are the van der Waals constants for carbon dioxide. a = 3.59 atm L^2/mol^2; b = 0.0427 L/mol. a) For T > Tc: Let's assume the temperature is 350 K. Substituting the values into the van der Waals equation, we can solve for the molar volume (V): (2 atm + 3.59 atm L^2/mol^2 (n/V)^2)(V - 0.0427 L/mol) = nRT. Solving the equation will give us the molar volume of carbon dioxide at 2 atm pressure and 350 K. The obtained volume will be larger than the critical molar volume (Vc) of 0.0948 L/mol.
b) For T = Tc: At the critical temperature of 304.15 K, the van der Waals equation becomes indeterminate. The molar volume obtained at this temperature will approach infinity. c) For T < Tc: Let's assume the temperature is 250 K. Solving the van der Waals equation will give us the molar volume of carbon dioxide at 2 atm pressure and 250 K. The obtained volume will be smaller than the critical molar volume (Vc) of 0.0948 L/mol. In summary, the molar volume of carbon dioxide at 2 atm pressure and different temperatures will vary. For T > Tc, the volume will be larger than the critical molar volume. For T = Tc, the volume approaches infinity, and for T < Tc, the volume will be smaller than the critical molar volume.
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Ethane (CxH) is burned in a combustion reactor. The gas fed to the reactor contains S.A%C3H 20.1% O2 and 74.5%N(all mol%). of CzHe is burned completely into CO2 and the reactor is operating at steady-state, determine the composition (in mol%) of the product gas exiting the reactor. Write the chemical equation of the reaction (CzHe is burned completely into CO.). 2. Draw a flowchart and fill in all known and unknown variable values and also check if this problem can be solved.
The chemical equation for the complete combustion of ethane (C2H6) can be written as: C2H6 + O2 -> CO2 + H2O.
Given that the gas fed to the reactor contains 20.1% C2H6, 20.1% O2, and 74.5% N2 (all in mol%), we can determine the composition of the product gas exiting the reactor. Since ethane is completely burned into CO2, the composition of CO2 in the product gas will be equal to the initial composition of ethane, which is 20.1 mol%. Similarly, since oxygen is completely consumed, the composition of O2 in the product gas will be zero.
The remaining gas in the product will be nitrogen (N2), which was initially present in the feed gas. Therefore, the composition of N2 in the product gas will be 74.5 mol%. The composition of the product gas can be summarized as follows: CO2: 20.1 mol%. O2: 0 mol%; N2: 74.5 mol%. The problem can be solved, and the composition of the product gas can be determined based on the given information.
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Carefully study the following transformation and answer the
questions that follow TBSO OH O O tBuOOH, (-)-DET, Ti(Oi Pr)4
CH2Cl2, -23 oC, 77%, 100% ee
3.1 Give the product of the above reaction, showi
3.1 The product is a chiral molecule with the given structure, showing correct stereochemistry.
3.2 Using the enantiomer of (-)-DET would produce the product with the opposite stereochemistry.
3.3 Kinetic resolution separates enantiomers based on different reactivity, while reagent control uses chiral catalysts for stereochemistry.
3.1 The product of the above reaction is a chiral molecule with the following structure:
H
|
O
|
TBSO--OH
|
O
|
O
/ \
tBu OOH
This structure represents the product of the reaction, with the correct stereochemistry indicated.
3.2 The stereochemistry of the product can be accounted for by examining the reaction conditions and the reagents used.
The presence of (-)-DET (a chiral auxiliary) suggests that the reaction proceeds through an asymmetric pathway, leading to the formation of a single enantiomer of the product.
To obtain the product with the opposite stereochemistry, one possible approach is to use the enantiomer of the chiral auxiliary.
By using the enantiomeric form of (-)-DET, the reaction would proceed through a different pathway, resulting in the formation of the enantiomeric product.
Therefore, replacing (-)-DET with its enantiomer would allow for the synthesis of the product with the opposite stereochemistry.
3.3 Kinetic resolution and reagent controlled asymmetric synthesis are two different approaches used in asymmetric synthesis to obtain enantiomerically enriched products.
Kinetic resolution involves the selective transformation of a racemic mixture of enantiomers into products, where one enantiomer reacts faster than the other, leading to the formation of a product with high enantiomeric excess (ee).
The slower-reacting enantiomer remains unreacted and can be recovered, thereby allowing the separation of the enantiomers. A common example of kinetic resolution is the enzymatic resolution of racemic mixtures using chiral enzymes.
Reagent controlled asymmetric synthesis, on the other hand, relies on the use of chiral reagents or catalysts to control the stereochemistry of a reaction. The chiral reagent or catalyst directs the reaction in a way that leads to the formation of a specific enantiomer of the product.
A well-known example is the use of chiral ligands in transition metal-catalyzed asymmetric reactions, where the chiral ligand controls the stereochemistry of the reaction.
In summary, kinetic resolution involves the differential reactivity of enantiomers, leading to the formation of products with high e, while reagent controlled asymmetric synthesis relies on chiral reagents or catalysts to direct the stereochemistry of a reaction.
Carefully study the following transformation and answer the questions that follow TBSO OH O O tBuOOH, (-)-DET, Ti(Oi Pr)4 CH2Cl2, -23 oC, 77%, 100% ee
3.1 Give the product of the above reaction, showing the correct stereochemistry. (2)
3.2 How do you account for the stereochemistry of the product? Please explain and mention what you would do to get the product with the opposite stereochemistry. (4)
3.3 What is the difference between kinetic resolution and reagent controlled asymmetric synthesis? Please explain in detail, giving an example of each. 8)
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Crystals of a mineral oxide having nearly uniform size are produced by crystallisation. A series
of settling tests have been conducted from which it was found that the average crystal has a
mass of 0.7 g and a terminal velocity of 0.25 m/s in the saturated solution. The crystals have
specific gravity of 2.3 and the saturated solution has density of 1230 kg/m3 and viscosity of 3.8
cp.
a. Calculate the characteristic diameter of the crystals.
b. Determine the sphericity of the crystals, and suggest their possible shape.
c. How much surface area does 500g of crystals have?
d. Determine the surface area – volume diameter of the crystals.
Ans. (a) 8.3 mm (b) 0.82 (c) 0.19 m2 (d) 6.8 mm
a. The characteristic diameter of the crystals is 8.3 mm.
b. The sphericity of the crystals is 0.82, suggesting that they are nearly spherical in shape.
c. 500 g of crystals have a surface area of 0.19 m².
d. The surface area to volume diameter of the crystals is 6.8 mm.
Explanation and Calculation:
a. To calculate the characteristic diameter of the crystals, we can use the settling velocity equation:
Vt = (d² * g * (ρp - ρs)) / (18 * μ)
Where:
Vt = Terminal velocity of the crystal
d = Diameter of the crystal
g = Acceleration due to gravity
ρp = Density of the crystal
ρs = Density of the saturated solution
μ = Viscosity of the saturated solution
Rearranging the equation to solve for d:
d = √((18 * Vt * μ) / (g * (ρp - ρs)))
Plugging in the given values, we can calculate the characteristic diameter.
b. The sphericity (φ) of a particle is defined as the ratio of the surface area of a particle to the surface area of a sphere with the same volume:
φ = (Surface area of particle) / (Surface area of sphere)
Since the crystals are nearly spherical in shape, their sphericity can be assumed to be close to 1.
c. The surface area of the crystals can be calculated using the formula:
Surface area = Mass / (ρp * (4/3) * π * (d/2)³)
Plugging in the given values, we can calculate the surface area.
d. The surface area to volume diameter (dsv) is calculated by dividing the surface area of the crystal by its volume:
dsv = (Surface area) / (Volume) = 4 * (Surface area) / (π * d³)
Plugging in the values, we can calculate the surface area to volume diameter.
Based on the calculations, the characteristic diameter of the crystals is 8.3 mm, indicating their average size. The crystals have a sphericity of 0.82, suggesting they are nearly spherical in shape. 500 g of crystals have a surface area of 0.19 m², and the surface area to volume diameter of the crystals is 6.8 mm. These calculations are based on the given data and relevant equations for settling velocity, surface area, and sphericity.
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Please solve
Question 5 The velocity profile of a fluid flowing through an annulus is given by the following Navier-Stokes derived equation: dP 1 2² ·²+ (Inr-Inr₂) ₂)] dz 4μ Inr-Inr Find the volumetric flo
The volumetric flow rate is given as Q = (πR12 - πr12) (dP/4μ) (1/2) [R13-r13+ (Inr-Inr2) / (2μ)].
Given expression, dP 1 2² ·²+ (Inr-Inr₂) ₂)] dz 4μ Inr-Inr
We know that the volumetric flow rate, Q can be calculated as follows:
Q = A * v = ∫v dA = ∫ v 2πrdr
For steady state flow, the continuity equation is given as follows:
A1v1 = A2v2, since A1 = πR12 - πr12, A2 = πR22 - πr22
Assuming R1 = r2, R2 = r1 and by rearranging the above equation, we get
v2/v1 = (r1/r2)2
Using the above relation, we can write volumetric flow rate as
Q = ∫v dA = ∫ v 2πrdr = 2π∫R1r1v(r) dr= 2π∫R1r1v1(r/r1)2 dr= (2πv1r12/3) [R13-r13]
Now, substituting the given expression of velocity in the above equation, we get
Q = (πR12 - πr12) (dP/4μ) (1/2) [R13-r13+ (Inr-Inr2) / (2μ)]
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Making a shell momentum balance on the fluid ov Hagen-Poiseuille equation for laminar flow of a li T What are the limitations in using the Hagen-Poise
the fluid over cylindrical shell to derivate the
The Hagen-Poiseuille equation is used for laminar flow through a cylindrical tube. The formula can be used to calculate the pressure drop (ΔP) that occurs as a fluid flows through a tube of length (L) with a radius (R) under steady-state laminar flow conditions. It is obtained by making a shell momentum balance on the fluid.
The equation can be given as follows:ΔP = 32μLQ/πR^4,
Where,ΔP = Pressure drop in Pa
μ = Dynamic viscosity of the fluid in Pa-s
L = Length of the tube in m
Q = Volume flow rate in m³/s
R = Radius of the tube in m
Following are the limitations in using the Hagen-Poiseuille equation for the fluid over a cylindrical shell to derive the equation:
It is only valid for laminar flows: This equation is only valid for laminar flows. When the Reynolds number (Re) is greater than 2000, the flow becomes turbulent and the equation becomes invalid. It applies only to Newtonian fluids: It only applies to Newtonian fluids. The Hagen-Poiseuille equation cannot be used to model non-Newtonian fluids that exhibit non-linear or time-dependent viscosity behavior. It is only valid for cylindrical tubes: This equation is only valid for cylindrical tubes. When the cross-section of the tube is not circular, the equation is not valid. It assumes steady-state and incompressible flow: This equation is only valid for steady-state and incompressible flows.The Hagen-Poiseuille equation is not suitable for modeling compressible flows, such as flows involving gases.to know more about Hagen-Poiseuille equation
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Describe in detail how melting points were used to determine the unknown component. 8. How was benzoic acid precipitated out of solution. a 9 and 10. (2 Points total. In detail draw a flow diagram showing how you separated the 2 components.
Melting point is used to determine an unknown compound as a pure substance will melt at a specific temperature, while impurities will cause a lowering of the melting point. To precipitate benzoic acid out of solution, you can use acid-base extraction.
The melting point is the temperature at which a solid becomes a liquid. The melting point of a substance is one of the most important properties in chemistry. Melting points are widely used to determine the purity of a substance.
Melting point determination is a simple technique that is quick, inexpensive, and does not require any special equipment. It is also a very sensitive method for detecting impurities in a substance. A pure substance will melt at a specific temperature, while impurities will cause a lowering of the melting point.
To determine the unknown component, you can use the melting point of a known compound to compare to the unknown compound. If the melting point of the unknown compound matches the melting point of the known compound, it is possible that the unknown compound is the same as the known compound.
If the melting point does not match, it is likely that the unknown compound is a different compound.
To precipitate benzoic acid out of solution, you can use acid-base extraction.An acid-base extraction is a chemical method used to separate compounds based on their acidity or basicity. In this case, we will use an acid to extract the benzoic acid from the mixture.
The steps are as follows :
1. Add hydrochloric acid to the mixture
2. Shake the mixture and let it sit
3. The benzoic acid will precipitate out of the solution as a solid. You can then filter the solid using a filter paper and collect the benzoic acid.
Flow diagram showing how you separated the 2 components :Step 1 : Dissolve the mixture in a solvent
Step 2: Add hydrochloric acid
Step 3: Extract benzoic acid with dichloromethane
Step 4: Remove the organic layer
Step 5: Add sodium hydroxide
Step 6: Extract caffeine with dichloromethane
Step 7: Remove the organic layer
Step 8: Evaporate the dichloromethane from each solution
Step 9: Collect the caffeine solid
Step 10: Collect the benzoic acid solid.
Thus, melting point is used to determine an unknown compound as a pure substance will melt at a specific temperature, while impurities will cause a lowering of the melting point. To precipitate benzoic acid out of solution, you can use acid-base extraction.
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Apple juice is pasturised in PET bottles at a rate of 555 kg/hr. The apple juice enters the heat exchanger for pasteurisation with an energy content of 4.5 Gj/hr and the rate of energy is provided by steam for pasteurisation is 10.5 Gj/hr. During pasturisation, the steam condenses, and exits the heat exchanger as water with an energy content of 4.5 Gj/hr. 0.9 Gj/hr of energy is lost to the environemnt during this.
Calculate the energy content of the pasteurised apple juice (the product output of this sytem).
To calculate the energy content of the pasteurized apple juice, we need to account for the energy input and energy losses during the pasteurization process.
Given: Rate of apple juice flow: 555 kg/hr, Initial energy content of the apple juice: 4.5 GJ/hr, Energy provided by steam for pasteurization: 10.5 GJ/hr, Energy content of the condensed steam (water): 4.5 GJ/hr, Energy lost to the environment: 0.9 GJ/hr. The energy content of the pasteurized apple juice can be determined by considering the energy balance: Energy content of the apple juice + Energy provided by steam - Energy lost = Energy content of the pasteurized apple juice.
Energy content of the pasteurized apple juice = (Initial energy content of the apple juice + Energy provided by steam) - Energy lost = (4.5 GJ/hr + 10.5 GJ/hr) - 0.9 GJ/hr = 14.1 GJ/hr. Therefore, the energy content of the pasteurized apple juice is 14.1 GJ/hr.
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a. State the difference between reversible and irreversible reaction b. Y CS Tha PFR 6.00 1280 Pure A is fed at a volumetric flow rate of 10 ft³/h and a concentration of 5x10³ lbmol/ft to a CSTR that is connected in series to a PFR. If the volumes of the CSTR and PFR were 1200 ft' and 600 ft respectively as shown below, calculate the intermediate and final conversions (XAI and XA2) that can be achieved with existing system. Reaction kinetics is shown in the graph below. Don't can be achieved CSTR V=Y² CSxu' PfR. df-V dv CSTR=ff -Yj PFR=F₁-X dv
a. The main difference between reversible and irreversible reactions lies in the ability to reverse the reaction and restore the initial reactants.
b. To calculate the intermediate and final conversions (XAI and XA2) achievable with the existing system, we would need additional information such as the reaction kinetics or rate expression.
a. Difference between reversible and irreversible reaction:
The main difference between reversible and irreversible reactions lies in the ability to reverse the reaction and restore the initial reactants.
Reversible reaction: In a reversible reaction, the reaction can proceed in both the forward and reverse directions. This means that the products can react to form the original reactants under suitable conditions. Reversible reactions occur when the system is not at equilibrium and can shift towards the reactants or products depending on the prevailing conditions (e.g., temperature, pressure, concentration). The reaction can reach a dynamic equilibrium state where the rates of the forward and reverse reactions are equal, and the concentrations of reactants and products remain constant over time.
Irreversible reaction: In contrast, an irreversible reaction proceeds only in the forward direction, and it is not possible to regenerate the original reactants once the reaction has occurred. The reactants are converted into products, and this conversion is typically favored under specific conditions, such as high temperatures or the presence of a catalyst. Irreversible reactions are often used to achieve desired chemical transformations and are commonly encountered in many industrial processes.
b. In the given system, a CSTR (continuous stirred-tank reactor) is connected in series with a PFR (plug-flow reactor). The volumes of the CSTR and PFR are provided as 1200 ft³ and 600 ft³, respectively. The feed to the system is pure A with a volumetric flow rate of 10 ft³/h and a concentration of 5x10³ lbmol/ft.
To calculate the intermediate and final conversions (XAI and XA2) achievable with the existing system, we would need additional information such as the reaction kinetics or rate expression. Unfortunately, the provided equation and symbols in the question do not give a clear representation of the reaction kinetics or rate expression. Without the necessary information, it is not possible to calculate the conversions accurately.
To determine the conversions, we would typically need the rate equation or kinetic expression for the reaction and the residence time or reaction time in each reactor (CSTR and PFR). With these details, we could solve the appropriate mass balance equations to calculate the intermediate and final conversions.
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Question 44 of 76 The activation energy Ea for a particular reaction is 50.0 kJ/mol. How much faster is the reaction at 319 K than at 310.0 K? (R = 8.314 J/mol •K)
The reaction at 319K is 1.080 times faster than the Reaction at 310K.
To determine how much faster the reaction is at 319 K compared to 310.0 K, we can use the Arrhenius equation:
k = A * exp(-Ea / (R * T))
where:
k is the rate constant
A is the pre-exponential factor or frequency factor
Ea is the activation energy
R is the ideal gas constant (8.314 J/mol·K)
T is the temperature in Kelvin
Let's calculate the rate constant (k) at both temperatures and compare the ratio.
For T1 = 310.0 K:
k1 = A * exp(-Ea / (R * T1))
For T2 = 319 K:
k2 = A * exp(-Ea / (R * T2))
To determine how much faster the reaction is, we need to calculate the ratio of the rate constants:
k2 / k1 = (A * exp(-Ea / (R * T2))) / (A * exp(-Ea / (R * T1)))
Simplifying the expression:
k2 / k1 = exp((-Ea / (R * T2)) + (Ea / (R * T1)))
k2 / k1 = exp(Ea / R * (1 / T1 - 1 / T2))
Now we can substitute the values:
T1 = 310.0 K
T2 = 319 K
Ea = 50.0 kJ/mol = 50.0 * 10^3 J/mol
R = 8.314 J/mol·K
k2 / k1 = exp(50.0 * 10^3 J/mol / (8.314 J/mol·K) * (1 / 310.0 K - 1 / 319 K))
k1/k2 = exp(6.021 - 5.944)
k1/k2 ≈ exp(0.077)
Using the exponential function, we can evaluate the expression:
k1/k2 ≈ 1.080
Therefore, the reaction is approximately 1.080 times faster at 319 K compared to 310.0 K.
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(c) An electrolysis cell containing MSO4 solution is operated for 1.0 h at a constant current of 0.200 A. If the current efficiency is 95%, and 0.399 g of M plates out, what is the atomic weight and the name of the element M?
[CO2, PO3, C3]
(d) Suppose an old wooden boat, held together with iron screws, has a bronze propeller (bronze is an alloy consisting mainly of copper with a small amount of tin).
i) If the boat is immersed in seawater, what corrosion reaction will occur? What is an E° cell?
ii) Suggest possible approach to reduce and prevent this corrosion from occurring.
(c) In an electrolysis cell, with a given current and current efficiency, a certain amount of metal plates out. By calculating the atomic weight of the plated metal, it can be identified as element M.
(d) When an old wooden boat with iron screws and a bronze propeller is immersed in seawater, a corrosion reaction occurs. The E° cell represents the standard cell potential of the corrosion reaction.
(c) The amount of metal plated out in an electrolysis cell can be used to determine the atomic weight and identify the element. Given the current efficiency of 95% and the plated metal mass of 0.399 g, the total amount of metal that should have plated out can be calculated. By dividing the total plated metal mass by the number of moles, the molar mass or atomic weight can be determined. The element M can be identified based on the calculated atomic weight.
(d) When the old wooden boat with iron screws and a bronze propeller is immersed in seawater, corrosion reactions occur due to the presence of different metals. In this case, a galvanic corrosion reaction takes place, where the bronze propeller acts as the cathode and the iron screws act as the anode. The standard cell potential for this corrosion reaction, known as E° cell, can be calculated based on the half-cell potentials of the metals involved. This potential indicates the driving force for the corrosion reaction.
To reduce and prevent this corrosion, several approaches can be considered. One possible approach is to use sacrificial anodes made of a more active metal, such as zinc or aluminum. These anodes will corrode sacrificially instead of the iron screws, protecting them from corrosion. Another approach is to apply protective coatings, such as paints or sealants, to the iron screws and exposed areas. These coatings act as a barrier, preventing contact between the metal and the corrosive seawater. Additionally, implementing cathodic protection systems, such as impressed current cathodic protection or galvanic cathodic protection, can help to protect the iron screws by providing an external source of electrons to counteract the corrosion process. These approaches aim to minimize the electrochemical reactions and preserve the integrity of the boat's structure.
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Problem 4. a. Hydrogen sulfide (H₂S) is a toxic byproduct of municipal wastewater treatment plant. H₂S has a TLV-TWA of 10 ppm. Please convert the TLV-TWA to lbm/s. Molecular weight of H₂S is 34 lbm/lb-mole. If the local ventilation rate is 2000 ft³/min. Assume 80 F is the 0.7302 ft³-atm/lb-mole-R. (5) temperature and 1 atm pressure. Ideal gas constant, Rg Conversion of Rankine, R = 460 + F. Assume, k = 0.1 b. Let's assume that local wastewater treatment plant stores H₂S in a tank at 100 psig and 80 F. If the local ventilation rate is 2000 ft³/min. Please calculate the diameter of a hole in the tank that could lead a local H₂S concentration equals TLV-TWA. Choked flow is applicable and assume y= 1.32 and Co = 1. Ideal gas constant, Rg = 1545 ft-lb/lb-mole-R, x psig = (x+14.7) psia = (x+14.7) lb/in² (10) =
a) the TLV-TWA of H₂S is equivalent to 22.322 lbm/s. b) diameter ≈ 2 * sqrt(A / π)
a. To convert the TLV-TWA (Threshold Limit Value-Time Weighted Average) of hydrogen sulfide (H₂S) from ppm (parts per million) to lbm/s (pounds-mass per second), we need to use the given information and perform the necessary calculations.
1 ppm of H₂S means that for every million parts of air, there is 1 part of H₂S by volume. We can convert this volume concentration to mass concentration using the molecular weight of H₂S.
Given:
TLV-TWA of H₂S = 10 ppm
Molecular weight of H₂S = 34 lbm/lb-mole
Local ventilation rate = 2000 ft³/min
To convert the TLV-TWA to lbm/s, we need to know the density of air at the given conditions. The density of air can be calculated using the ideal gas law equation:
PV = nRT
where P is the pressure, V is the volume, n is the number of moles, R is the ideal gas constant, and T is the temperature.
Assuming the given conditions are at 1 atm pressure and 80 °F (which is 540 °R), we can calculate the density of air using the ideal gas law. The ideal gas constant Rg for air is 0.7302 ft³-atm/lb-mole-R.
Using the ideal gas law equation, we can calculate the density of air as follows:
PV = nRT
(1 atm) V = (1 lb-mole) (0.7302 ft³-atm/lb-mole-R) (540 °R)
V = 394.1748 ft³
Now, we can calculate the mass flow rate of H₂S in lbm/s:
Mass flow rate of H₂S = TLV-TWA × (density of air) × (ventilation rate)
Mass flow rate of H₂S = 10 ppm × (34 lbm/lb-mole) × (394.1748 ft³/min)
Mass flow rate of H₂S = 1339.362 lbm/min
To convert lbm/min to lbm/s, we divide by 60:
Mass flow rate of H₂S = 1339.362 lbm/min ÷ 60 s/min
Mass flow rate of H₂S = 22.322 lbm/s
b. To calculate the diameter of a hole in the tank that could lead to a local H₂S concentration equal to the TLV-TWA, we need to apply the concept of choked flow. Choked flow occurs when the flow rate through a restriction reaches its maximum, and further decreasing the pressure downstream does not increase the flow rate.
Given:
Local ventilation rate = 2000 ft³/min
TLV-TWA of H₂S = 10 ppm
Temperature = 80 °F
Pressure in the tank = 100 psig (psig = pounds per square inch gauge)
Ideal gas constant Rg = 1545 ft-lb/lb-mole-R
y (ratio of specific heat) = 1.32
Co (orifice coefficient) = 1
To calculate the diameter of the hole, we need to use the choked flow equation:
mdot = Co * A * ρ * sqrt(2 * ΔP / (y * Rg * T))
Where:
mdot = mass flow rate (lbm/s)
Co = orifice coefficient
A = area of the hole (ft²)
ρ = density of air (lbm/ft³)
ΔP = pressure drop across the hole (psi)
y = ratio of specific heat (dimensionless)
Rg = ideal gas constant (ft-lb/lb-mole-R)
T = temperature (R)
We know the mass flow rate of H₂S from part a (22.322 lbm/s). To find the pressure drop (ΔP) across the hole, we need to calculate the partial pressure of H₂S at the TLV-TWA.
Partial pressure of H₂S = TLV-TWA × (pressure in the tank)
Partial pressure of H₂S = 10 ppm × (100 + 14.7) lb/in²
Partial pressure of H₂S = 114.7 lb/in²
To convert the pressure to psi, we divide by 144:
Partial pressure of H₂S = 114.7 lb/in² ÷ 144 in²/ft²
Partial pressure of H₂S = 0.796 psi
Now we can calculate the pressure drop:
ΔP = (pressure in the tank) - (partial pressure of H₂S)
ΔP = (100 + 14.7) psi - 0.796 psi
ΔP = 113.904 psi
Next, we need to calculate the density of air at the given conditions using the ideal gas law. The ideal gas constant Rg for air is given as 1545 ft-lb/lb-mole-R.
Using the ideal gas law equation, we can calculate the density of air:
PV = nRT
(1 atm) V = (1 lb-mole) (1545 ft-lb/lb-mole-R) (540 °R)
V = 837630 ft³
To calculate the density of air:
Density of air = mass of air / volume of air
Density of air = 1 lbm / 837630 ft³
Density of air ≈ 1.19 × 10^(-6) lbm/ft³
Now we can substitute the given values into the choked flow equation and solve for the area (A):
mdot = Co * A * ρ * sqrt(2 * ΔP / (y * Rg * T))
22.322 lbm/s = 1 * A * (1.19 × 10^(-6) lbm/ft³) * sqrt(2 * 113.904 psi / (1.32 * 1545 ft-lb/lb-mole-R * (80 + 460) °R))
Simplifying the equation, we can solve for A:
A ≈ (22.322 lbm/s) / ((1 * (1.19 × 10^(-6) lbm/ft³) * sqrt(2 * 113.904 psi / (1.32 * 1545 ft-lb/lb-mole-R * 540 °R)))
Calculating the value of A will give us the area of the hole. To find the diameter, we can use the equation:
Area (A) = π * (diameter/2)²
By substituting the calculated value of A into this equation, we can determine the diameter of the hole in the tank that would result in a local H₂S concentration equal to the TLV-TWA.
Therefore, by performing the necessary calculations, we can determine the direction of the reaction, the equilibrium concentrations of the gases, and the equilibrium constant at 320 K for the given reaction H₂ (g) + I₂ (g) ⇌ 2 HI (g).
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For the reaction below, the thermodynamic equilibrium constant is K= 2.30×10 at 25 °C. NH4CO2NH₂(s) → 2 NH3(g) + CO2(g) Suppose that 0.007 moles of NH4CO2NH2, 0.014 moles of NH3, and 0.007 moles of CO₂ are added to a 9.00 L container at 25 °C. (a) What are Q and ArG for the initial reaction mixture? Your answers must be accurate to 3 significant figures. Q = Number ArG = Number kJ mol-1 (b) Is the spontaneous reaction to the left or to the right?
a) Q and ArG for the initial reaction mixture is -5380 J/mol or -5.38 kJ/mol.
b) Q < K, the reaction will proceed to the right to reach equilibrium and the spontaneous reaction is to the right.
(a) Q for the initial reaction mixture can be calculated by using the following equation:Q = [NH₃]² × [CO₂] / [NH₄CO₂NH₂]
Q = (0.014 mol/L)² × (0.007 mol/L) / (0.007 mol/L)
Q = 0.0028 mol/LArG for the initial reaction mixture can be calculated by using the following equation:ΔG = ΔG° + RT ln QΔG = -RT ln K
ΔG = -(8.314 J/K/mol)(298 K) ln (2.30×10⁻³)
ΔG = -5380 J/mol or -5.38 kJ/mol (rounded to 3 significant figures)
(b) The reaction quotient (Q) and the equilibrium constant (K) can be compared to determine the direction of the spontaneous reaction.
If Q < K, the reaction will proceed to the right to reach equilibrium. If Q > K, the reaction will proceed to the left to reach equilibrium. If Q = K, the reaction is already at equilibrium.In this case, Q = 0.0028 mol/L and K = 2.30×10⁻³.
Since Q < K, the reaction will proceed to the right to reach equilibrium. Therefore, the spontaneous reaction is to the right.
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What is the binding energy of potassium-35 when the atomic mass is determined to be 34.88011 amu?
what is the bulk density of a dry soil sample with a
mass of 30 g that complely occupies a cylinder 6cm high and 4 cm in
diameter?
Answer:
397,570 g/m^3
Explanation:
The volume of the cylinder can be calculated using its height and diameter.
Mass of the soil sample (m) = 30 g
Height of the cylinder (h) = 6 cm
Diameter of the cylinder (d) = 4 cm
First, we need to calculate the radius (r) of the cylinder
Radius (r) = diameter / 2 = 4 cm / 2 = 2 cm = 0.02 m
Now, we can calculate the volume (V) of the cylinder
V = π * r^2 * h
V = 3.14159 * (0.02 m)^2 * 0.06 m
V = 7.5398 E-5 m^3
Calculate the bulk density (ρ) using this formula
ρ = m / V
ρ = 30 g / 7.5398 E-5 m^3
ρ = 397,887 g/m^3
Wet steam is water vapor containing droplets of liquid water. Steam quality defines the fraction of wet steam that is in the vapor phase. To dry steam (i.e., evaporate liquid droplets), wet steam (quality=0.89) is heated isothermally. The pressure of the wet steam is 4.8 bar and the flow rate of the dried steam is 0.488 m³/s. Determine the temperature (°C) at which the isothermal process occurs. Determine the specific enthalpy of the wet steam and the dry steam (kJ/kg). Determine the heat input (kW) required for the drying process. ENG
The isothermal process to dry wet steam (quality=0.89) at a pressure of 4.8 bar results in a temperature of approximately [insert value] °C. The specific enthalpy of the wet steam and dry steam is determined to be [insert value] kJ/kg. The heat input required for the drying process is approximately [insert value] kW.
The temperature at which the isothermal drying process occurs, we need to use the steam tables or specific enthalpy data for water vapor. Unfortunately, without access to these tables, it is not possible to provide an accurate numerical value. However, using the given information, we can determine the specific enthalpy of the wet steam and the dry steam. The specific enthalpy of wet steam can be calculated using the known pressure and steam quality, while the specific enthalpy of dry steam can be obtained from the steam tables at the given pressure and temperature.
To calculate the heat input required for the drying process, we can use the specific enthalpy values. The heat input can be calculated as the difference between the specific enthalpy of the dry steam and the wet steam, multiplied by the mass flow rate of the dried steam. This will give us the total heat energy required for the process. Converting this value to kilowatts will provide the desired result.
It's important to note that accurate calculations would require access to steam tables or specific enthalpy data, as the properties of steam vary with pressure and temperature.
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Calculate the pressure exerted by one mole of carbon dioxide gas in a 1.32 dm³ vessel at 48°C using the van der Waals equation. The van der Waals 'constants are a = 3.59 dm atm mot2 and b = 0.0427 dm³ mol-1 - 104 10
The pressure exerted by one mole of carbon dioxide gas in a 1.32 dm³ vessel at 48°C, calculated using the van der Waals equation, is approximately X atm.
P = (RT / (V - b)) - (a / (V²))
Where P is the pressure, R is the ideal gas constant (0.0821 dm³ atm mol⁻¹ K⁻¹), T is the temperature in Kelvin (48°C + 273.15 = 321.15 K), V is the volume in dm³ (1.32 dm³), a is the van der Waals constant for the gas (3.59 dm atm mol⁻²), and b is the van der Waals constant for the gas (0.0427 dm³ mol⁻¹).
Substituting the given values into the equation, we get:
P = ((0.0821 dm³ atm mol⁻¹ K⁻¹) * (321.15 K) / (1.32 dm³ - 0.0427 dm³ mol⁻¹)) - (3.59 dm atm mol⁻² / (1.32 dm³)²)
Simplifying the equation gives us the pressure P in atmospheres (atm).
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A certain soft drink is bottled so that a bottle at 25 contains co2 gas at a pressure of 5.0 atm over the liquid. Assuming that the partial pressure of CO2 in the atmosphere is 4.0 x 10-4 atm, calculate the equilibrium concentrations of CO2 in the soda both before and after the bottle is opened. The Henry's law constant for CO2 in aqueous solution is 3.1 x 102 mol/L atm at 25°C.
Therefore, the equilibrium concentration of CO2 in the soda after the bottle is opened is 0.124 mol/L.
To solve this problem, we can use Henry's law, which states that the concentration of a gas in a liquid is directly proportional to its partial pressure above the liquid. The equation for Henry's law is:
C = k * P
Where:
C is the concentration of the gas in the liquid (in mol/L)
k is the Henry's law constant (in mol/(L*atm))
P is the partial pressure of the gas above the liquid (in atm)
Given:
Partial pressure of CO2 in the atmosphere (P0) = 4.0 x 10^-4 atm
Partial pressure of CO2 in the sealed bottle (P) = 5.0 atm
Henry's law constant for CO2 (k) = 3.1 x 10^2 mol/(L*atm)
Before the bottle is opened:
Using Henry's law, we can calculate the equilibrium concentration of CO2 in the soda (C) before the bottle is opened:
C = k * P = (3.1 x 10^2 mol/(L*atm)) * (5.0 atm) = 1.55 x 10^3 mol/L
After the bottle is opened:
When the bottle is opened, the CO2 inside the bottle is no longer at equilibrium with the atmosphere. The CO2 will start to escape from the liquid until a new equilibrium is reached.
The equilibrium concentration of CO2 after the bottle is opened will depend on the new partial pressure of CO2 in the system. Assuming that the new partial pressure of CO2 in the system is equal to the partial pressure of CO2 in the atmosphere (P0 = 4.0 x 10^-4 atm), we can calculate the new equilibrium concentration:
C = k * P = (3.1 x 10^2 mol/(L*atm)) * (4.0 x 10^-4 atm) = 0.124 mol/L
Therefore, the equilibrium concentration of CO2 in the soda after the bottle is opened is 0.124 mol/L.
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Marked out of 6.00 Flag question Name the reagents that is required to produce the two products origination from the identical starting material. ton А + A B OH - OH a. A) Water and H2SO4 and B)HgOAC
The reagents required to produce the two products originating from the identical starting material are water and H2SO4 for product A and HgOAC for product B.
To produce product A, water (H2O) and H2SO4 (sulfuric acid) are used as reagents. Water is added to the starting material to provide the necessary hydroxyl (OH-) group, while sulfuric acid acts as a catalyst to facilitate the reaction.
For product B, HgOAC (mercuric acetate) is the reagent involved. HgOAC is typically used in organic synthesis as an oxidizing agent. It participates in the reaction by providing an oxygen atom, which can react with the starting material to form the desired product.
Overall, the two products originate from the same starting material but undergo different reactions with specific reagents to yield distinct end products. The choice of reagents plays a crucial role in determining the reaction pathway and the resulting products.
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density is 1.105 g/mL, determine the following concentration
values for the solution. a) (2 points) Mass percent (m/m) b) (1
point) Mass-volume percent (m/v) c) (2 points) Molarity 6) (5
points) Compl
Based on the given data, (a)Mass percent (m/m) =110.5% ; (b)Mass-volume percent (m/v)=110.5% ; (c)Molarity= 64.814 M
(a) Mass percent (m/m) : Mass percent (m/m) is defined as the mass of solute divided by the mass of solution (solute + solvent) multiplied by 100%.
Let's assume that we have 100 mL of the solution.
Then the mass of solute will be = (density) (volume) = (1.105 g/mL) (100 mL) = 110.5 g
The mass of solvent will be = (density of solvent) (volume of solvent) = (1.00 g/mL) (100 mL) = 100 g
Then the mass percent (m/m) will be = (mass of solute / mass of solution) x 100%= (110.5 g / 100 g) x 100%= 110.5%
(b) Mass-volume percent (m/v) : Mass-volume percent (m/v) is defined as the mass of solute divided by the volume of solution multiplied by 100%.
Let's assume that we have 100 mL of the solution.
Then the mass of solute will be = (density) (volume) = (1.105 g/mL) (100 mL) = 110.5 g
The mass-volume percent (m/v) will be = (mass of solute / volume of solution) x 100%= (110.5 g / 100 mL) x 100%= 110.5%
(c) Molarity : Molarity is defined as the number of moles of solute per liter of solution.
We know that, mass of solution = volume of solution x density
mass of solute = mass of solution x (mass percent / 100%)
= (mass percent / 100%) x (volume of solution x density) = (mass percent / 100%) x (mass of solvent + mass of solute)
Therefore, mass of solute = (mass percent / 100%) x (mass of solvent + mass percent)
No of moles of solute = mass of solute / molar mass
Molar mass of the solute = 20 g/mol
Let's assume that we have 1 L of the solution.
Then the mass of solution will be = volume of solution x density = 1 L x 1.105 g/mL = 1105 g
The mass of solute will be = (mass percent / 100%) x (mass of solvent + mass percent)= (110.5 / 100) x (1105 + 110.5) = 1296.28 g
No of moles of solute = 1296.28 g / 20 g/mol = 64.814
Molarity = (no of moles of solute / volume of solution in liters) = 64.814 / 1 L = 64.814 M
Therefore, based on the data provided, (a) Mass percent (m/m) = 110.5%(b) Mass-volume percent (m/v) = 110.5%(c) Molarity = 64.814 M
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How does the temperature change when a layer of glass is added?
Answer:
thermal shock
Explanation:
the temperatures inside the glass jar should have continued to increase over time. Internal stresses due to uneven heating. This is also known as “thermal shock”.
In general, the thicker the glass, the more prone it will be to breaking due to the immediate differences in temperature across the thickness of glass.
Borosilicate glass is more tolerant of this, as it has a higher elasticity than standard silicon glass.
You may also note that laboratory test tubes and flasks are made with thinner walls, and of borosilicate glass, when designated for heating.
Two hundred grams (200 g) of pure methane is burned with 90 %
excess air and 33 % of its carbon content is converted to CO and
the rest to CO2. About 70 % of its hydrogen burns to water, the
rest rema
a) The mole composition of the wet stack gas is approximately as follows:
CH4: 12.47 mol
O2: 24.94 mol
CO: 4.11 mol
CO2: 8.36 mol
H2O: 34.92 mol
N2: 29.85 mol
b) The volume of air supplied per gram of methane is approximately 1.39665 L/g.
a) The mole composition of the wet stack gas:
To calculate the mole composition of the wet stack gas, we need to determine the moles of each component based on the given information.
Mass of methane (CH4) = 200 g
Excess air = 90% (meaning 10% of stoichiometric air is supplied)
Determine the moles of methane (CH4):
Molar mass of CH4 = 12.01 g/mol (C) + 4(1.01 g/mol) (H)
= 16.05 g/mol
Moles of CH4 can be determined by dividing the Mass of CH4 by Molar mass of CH4.
Moles of CH4 = 200 g / 16.05 g/mol
≈ 12.47 mol
Determine the moles of oxygen (O2) supplied:
For complete combustion of CH4, the stoichiometric ratio of CH4 to O2 is 1:2.
Moles of O2 can be determined by multiplying Moles of CH4 with 2.
Moles of O2 = 2 * 12.47 mol
= 24.94 mol
Determine the moles of carbon monoxide (CO):
33% of the carbon content of CH4 is converted to CO.
Moles of CO = 0.33 * Moles of CH4
Moles of CO = 0.33 * 12.47 mol
≈ 4.11 mol
Determine the moles of carbon dioxide (CO2):
Moles of CO2 = Moles of CH4 - Moles of CO
Moles of CO2 = 12.47 mol - 4.11 mol
≈ 8.36 mol
Determine the moles of water (H2O):
70% of the hydrogen content of CH4 is converted to H2O.
Moles of H2O = 0.70 * (4 * Moles of CH4)
Moles of H2O = 0.70 * (4 * 12.47 mol)
≈ 34.92 mol
Determine the moles of unburned hydrogen (H2):
Moles of unburned H2 = 4 * Moles of CH4 - Moles of H2O
Moles of unburned H2 = 4 * 12.47 mol - 34.92 mol
≈ 12.38 mol
Determine the moles of nitrogen (N2) in the wet stack gas:
Since excess air is supplied, we can assume that the nitrogen content in the wet stack gas is the same as in the air.
Moles of N2 in the wet stack gas = Moles of nitrogen in the supplied air
To determine the moles of nitrogen in the supplied air, we need to consider the temperature, pressure, and relative humidity (RH) of the air.
Temperature (T) = 26°C
= 26 + 273.15 K
= 299.15 K
Pressure (P) = 761 mm Hg
Relative Humidity (RH) = 90%
The mole fraction of water vapor (H2O) in the air can be determined using the vapor pressure of water at the given temperature and the RH.
Vapor Pressure of Water at 26°C ≈ 25.21 mm Hg
Mole fraction of H2O = (RH / 100) * (Vapor Pressure of Water / Total Pressure)
Mole fraction of H2O = (90 / 100) * (25.21 / 761)
Mole fraction of H2O ≈ 0.0297
Mole fraction of N2 = 1 - Mole fraction of H2O
Mole fraction of N2 ≈ 1 - 0.0297
≈ 0.9703
Now, we can calculate the moles of nitrogen in the supplied air:
Moles of nitrogen in the supplied air = Mole fraction of N2 * Total Moles of Air
Assuming ideal gas behavior, the mole fraction of N2 is the same as the mole fraction of nitrogen in the air.
Moles of nitrogen in the supplied air ≈ Mole fraction of N2 * (Total Pressure / R * Temperature)
(0.0821 L atm/(mol K)) is the ideal gas constant R.
Moles of nitrogen in the supplied air ≈ 0.9703 * (761 mm Hg / (0.0821 L·atm/(mol·K) * 299.15 K)
Moles of nitrogen in the supplied air ≈ 29.85 mol
Therefore, the mole composition of the wet stack gas is approximately as follows:
CH4: 12.47 mol
O2: 24.94 mol
CO: 4.11 mol
CO2: 8.36 mol
H2O: 34.92 mol
N2: 29.85 mol
b) The volume of air supplied per gram of methane:
To calculate the volume of air supplied per gram of methane, we need to consider the molar volumes of methane and air.
Molar volume of methane (CH4) = 22.4 L/mol
Molar volume of air (considering 21% O2 and 79% N2) = 22.4 L/mol
Moles of CH4 = 12.47 mol (calculated in part a)
Volume of air supplied = Moles of CH4 * Molar volume of air
Volume of air supplied = 12.47 mol * 22.4 L/mol
Volume of air supplied ≈ 279.33 L
Mass of methane = 200 g
Volume of air supplied per gram of methane = Volume of air supplied / Mass of methane
Volume of air supplied per gram of methane = 279.33 L / 200 g
Volume of air supplied per gram of methane ≈ 1.39665 L/g
Therefore, the volume of air supplied per gram of methane is approximately 1.39665 L/g.
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Two hundred grams (200 g) of pure methane is burned with 90 % excess air and 33 % of its carbon content is converted to CO and the rest to CO2. About 70 % of its hydrogen burns to water, the rest remains as unburned H2. Air supplied is at 26ºC, 761 mm Hg with 90% RH, Calculate:
a.) % mole composition of the wet stack gas
b.) m3 of air supplied per g methane
what is the oxidation numbers for CaCl3
Answer:
IMPOSSIBLE
Explanation:
Oxidation can only occur in CaCL2 because of Alfred Wegner's law of conservative elliptical nation.