A student carried out an experiment to find the mass of FeSO4.7H20 in an impure sample, X. The student recorded the mass of X. This sample was dissolved in water and made up to 250cm^3 of solution. The student found that, after an excess of acid had been added, 25.0cm^3 of this solution reacted with 21.3cm^3 of a 0.0150 moldm^-3 solution of K2Cr2O7. Use this information to calculate a value for the mass of FeSO4.7H20 in the sample X.

I understand the calculations part of the question, but i never understood how to work out the equation involved, which is:

6Fe2+ + Cr2O72- + 14H+ --> 6Fe3+ +2Cr3+ +7H2O

How do i work this out? Why are there 6 moles of Fe2+? what does it mean if there is an impurity, X? i am just really confused about this question if someone could elaborate clearly i will be really happy, thanks

Answers

Answer 1

I understand that you're looking for clarification on the balanced chemical equation and the concept of impurities. Let's break it down.

1. Balanced chemical equation:

The given balanced equation is:

6Fe2+ + Cr2O72- + 14H+ → 6Fe3+ + 2Cr3+ + 7H2O

To understand why there are 6 moles of Fe2+, you need to recognize that the coefficients in a balanced chemical equation represent the stoichiometric ratios between reactants and products. In this redox reaction, the Fe2+ ions are being oxidized to Fe3+ ions, and the Cr2O72- ions are being reduced to Cr3+ ions. The balanced equation is derived through balancing the charges and atoms on both sides of the equation, ensuring that the number of electrons transferred in the redox process is equal.

2. Impure sample X:

The problem states that the sample X is an impure sample of FeSO4.7H2O. This means that the sample contains FeSO4.7H2O as well as other substances (impurities) which do not participate in the reaction. These impurities do not affect the stoichiometry of the reaction but may contribute to the mass of the sample. The goal of the problem is to determine the mass of FeSO4.7H2O in the sample, disregarding the impurities.

Now, let's carry out the calculations to find the mass of FeSO4.7H2O in the sample X:

1. From the balanced equation, we know that 6 moles of Fe2+ react with 1 mole of Cr2O72-.

2. Calculate the moles of Cr2O72- used in the reaction from the volume and concentration of K2Cr2O7 solution:

Moles of Cr2O72- = Volume (dm^3) × Concentration (mol/dm^3)

Moles of Cr2O72- = 0.0213 dm^3 × 0.0150 mol/dm^3 = 3.195 × 10^-4 mol

3. Calculate the moles of Fe2+ in the 25.0 cm^3 aliquot of the 250 cm^3 FeSO4 solution:

Moles of Fe2+ = 6 × Moles of Cr2O72-

Moles of Fe2+ = 6 × 3.195 × 10^-4 mol = 1.917 × 10^-3 mol

4. Calculate the moles of Fe2+ in the entire 250 cm^3 FeSO4 solution:

1.917 × 10^-3 mol (in 25.0 cm^3) × (250 cm^3 / 25.0 cm^3) = 0.01917 mol

5. Calculate the mass of FeSO4.7H2O in the sample X:

Mass = Moles × Molar mass

Mass = 0.01917 mol × (151.91 + 7 × 18.015) g/mol = 0.01917 mol × 278.015 g/mol = 5.33 g (approximately)

Thus, the mass of FeSO4.7H2O in the impure sample X is approximately 5.33 g.


Related Questions

what is the PGE of a 257 kg boulder at the top of a 19 m cliff

Answers

The potential energy (PGE) of an object can be calculated using the formula: PGE = mgh, where m is the mass of the object, g is the acceleration due to gravity (approximately 9.8 m/s² on Earth), and h is the height or vertical distance.

Given:
Mass of the boulder (m) = 257 kg
Height of the cliff (h) = 19 m
Acceleration due to gravity (g) = 9.8 m/s²

Now we can calculate the potential energy:

PGE = (257 kg) × (9.8 m/s²) × (19 m)
PGE = 485,366 J

Therefore, the potential energy of the 257 kg boulder at the top of the 19 m cliff is approximately 485,366 joules (J).

What does percent composition tell you about a molecule?

Answers

Answer:

Percent composition tells you the relative amounts of each element in a molecule by mass. It can be used to determine the empirical formula of a compound, as well as to compare the composition of different molecules.

For example, the percent composition of water (H2O) is 11.19% hydrogen and 88.81% oxygen by mass. This tells us that there are two hydrogen atoms for every one oxygen atom in the molecule.

Explanation:

Brainliest Plsss

organic functional groups that are found in morphine but not in cannabinol

Answers

Organic functional groups found in morphine but not in cannabinol include:

1. Phenol group: Morphine contains a phenol group (-OH) attached to an aromatic ring, which is absent in cannabinol.

2. Ether group: Morphine possesses an ether functional group (-O-) in its structure, while cannabinol does not have this group.

3. Amino group: Morphine contains an amino group (-NH2), which is not present in cannabinol.

4. Tertiary amine group: Morphine has a tertiary amine group (-NR3), whereas cannabinol lacks this functional group.

5. Ester group: Ester functional groups (-COO-) are found in some morphine derivatives, but cannabinol does not possess this group.

It's important to note that while these functional groups differentiate morphine from cannabinol, the effects and properties of these compounds are determined by their overall chemical structure, not just the presence or absence of specific functional groups.

Which of the following types of radiation can penetrate the most deeply into your body? (2 points)

Alpha rays
Beta rays
Gamma rays
Proton rays

Answers

gamma rays penetrate the most deeply!!

With the aid of a clearly labelled diagram, explain the effect of substrate concentration on the rate of reaction catalysed by an allosteric enzyme

Answers

Allosteric enzymes change shape upon binding an effector molecule, displaying a sigmoidal substrate concentration vs. reaction rate curve. The reaction rate increases until saturation, characterized by the enzyme's Km.

Allosteric enzymes are enzymes that change their shape upon binding of another molecule, known as an effector, to a specific site, the allosteric site. These enzymes are essential for regulating metabolic pathways in cells.A graph of substrate concentration vs. reaction rate for an allosteric enzyme often displays a sigmoidal curve. The enzyme initially binds the substrate molecule with a relatively low affinity, which corresponds to a low reaction rate. However, as the substrate concentration increases, more enzyme-substrate complexes are formed, causing a conformational change in the enzyme that increases its affinity for substrate molecules at other sites. As a result, the reaction rate increases sharply, but only up to a certain point, after which it levels off. The substrate concentration at which the reaction rate is half of its maximum value is known as the enzyme's Michaelis-Menten constant (Km). A substrate concentration that exceeds the Km does not affect the reaction rate. The enzyme is saturated with substrate molecules, so it cannot bind anymore.

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A mass of 100 g of NaNO3 is dissolved in 100 g of water. At what temperature should solid crystals form?

Answers

A mass of 100 g of NaNO3 is dissolved in 100 g of water, at "31.2°C" temperature the solid crystals are form.

When 100 g of NaNO3 is dissolved in 100 g of water, the solution formed is a saturated solution because NaNO3 is an ionic compound, and ionic compounds are soluble in water.

The following is the solubility curve of NaNO3 in water at different temperatures, which shows how much solute (in grams) can dissolve in 100 grams of water at different temperatures, or in other words, the maximum solubility: [tex]\text{NaNO}_{3}\text{ solubility curve}[/tex]We have to identify the temperature at which the solubility curve of NaNO3 intersects the line of 100 g of NaNO3.

The intersection point is at 31.2°C. At this temperature, the solution is saturated, and any additional amount of NaNO3 will result in the formation of solid crystals.

As a result, the temperature at which solid crystals will form is 31.2°C.

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Explain the effect of Global Warming on land and sea breeze.

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Global warming affects land and sea breezes. It can weaken land breezes due to increased land temperatures and disrupt the timing and intensity of these breezes. Conversely, it can strengthen sea breezes with higher water temperatures and influence atmospheric conditions. Regional variations apply.

a Li+ wavelength in nm= 671 find the experimental energy in J and the n initial and n final by applying the equation E=-2.18*10^-18J(1/n^2final - 1/n^2initial)Z^2

Answers

The experimental energy in J and the n initial and n final by applying the equation in [tex]E= -4.21 * 10^{-19} J[/tex]

The given formula is[tex]E=-2.18*10^-18J(1/n^2final - 1/n^2initial)Z^2[/tex]

The formula to calculate the energy of a photon is given by:E= hc / λwhere:E = energy of a photonh = Planck's constantc = speed of lightλ = wavelength of the photon.

Given values are:

λ = 671 nmh = [tex]6.626 * 10-^{34}J.sc = 3.0 * 10^8 m/s[/tex]

By using the formulaE= hc / λE

= [tex]6.626 * 10^{-34} J.s * 3.0 * 10^{8} m/s / (671 * 10^{-9} m)E[/tex]

= [tex]2.96 * 10^{-19[/tex]J

Now, the energy of a photon in joules is found to be 2.96 × 10^-19 J. We will now find the n final and n initial. We need to find out the principle quantum numbers of n initial and n final. Let us apply the Rydberg formula to find out n initial and n final.

We know that:

λ = [tex]R [1/n^2final - 1/n^2initial][/tex]where:λ = 671 nm

n final  = ?n initial  = ?R = Rydberg constantR = [tex]1.097 * 10^7 m^{-1[/tex]

By substituting the given values, we get:

671 nm =[tex](1.097 * 107 m-1) [1/n^2final - 1/n^2initial][/tex]

On solving this, we get:n initial = 2n final = 1

By substituting the obtained values in the energy formula, we get:

[tex]E=-2.18*10^-18J(1/n^2final - 1/n^2initial)Z^2E=-2.18*10^-18J(1/1^2 - 1/2^2)(3^2)[/tex]

[tex]E= -4.21 * 10^{-19} J[/tex]

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Compare and contrast diffusion and convection and the impact on dispersal of air pollution.

Answers

Diffusion and convection are two distinct processes that play a role in the dispersal of air pollution, but they differ in how they transport pollutants and their impact on dispersion.

Diffusion refers to the spontaneous movement of particles from an area of higher concentration to an area of lower concentration. It occurs due to random thermal motion of molecules. In the context of air pollution, diffusion allows pollutants to spread out gradually, dispersing them in various directions. However, diffusion alone is a relatively slow process, particularly for large-scale dispersion, and it may not be effective in rapidly distributing pollutants over long distances.

Convection, on the other hand, involves the transfer of heat energy through the movement of a fluid, such as air or water. In the atmosphere, convection occurs as warm air rises, creating upward currents and transporting pollutants vertically. As the air rises, it carries pollutants to higher altitudes, which can lead to their dispersion over larger areas. Convection is a more efficient process for the vertical transport and dispersion of pollutants compared to diffusion.

The impact of diffusion and convection on the dispersal of air pollution can vary. Diffusion primarily affects local dispersion, allowing pollutants to spread out in the immediate vicinity of emission sources. It is more significant in areas with minimal air movement. Convection, on the other hand, can facilitate the long-range transport of pollutants, particularly when large-scale weather systems are involved. Convection can carry pollutants over greater distances and contribute to regional or even global dispersion, depending on weather patterns.

In summary, diffusion and convection are both involved in the dispersal of air pollution, but they differ in the mechanisms of transport and the scale of dispersion. Diffusion leads to gradual spreading of pollutants locally, while convection enables vertical transport and dispersion over larger areas, including long-range transport depending on weather conditions. Understanding the interplay between these processes is crucial for assessing the extent and impact of air pollution.

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combustion always result in to formation of water. what other type of reactions may result into formation of water? examples of these reactions​

Answers

As combustion always result into the formation of water, the other type of reactions that may result into formation of water are Acid-Base Neutralization Reactions and Hydrogen and Oxygen Reaction.

Acid-Base Neutralization Reactions:

A neutralisation reaction is a chemical process in which an acid and a base combine to produce salt and water as the end products.

H⁺ ions and OH⁻ ions combine to generate water during a neutralisation reaction. Acid-base neutralisation is the most common type of neutralisation reaction.

Example: Formation of Sodium Chloride (Common Salt):

HCl + NaOH → NaCl + H₂O

Hydrogen and Oxygen Reaction:

Water vapour is created when hydrogen gas (H₂) and oxygen gas (O₂) are combined directly. This reaction produces a lot of heat and releases a lot of energy.

Example: 2 H₂ + O₂ → 2 H₂O

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what is the equivalent resistance of this circuit

Answers

Answer: 100 ohms.

Explanation:

The circuit is composed of two parallel branches (upper and lower), with one resistor in the upper branch (150) and two resistors in the lower branch (250 and 50).

The lower branch resistors are in series, so the lower branch's resistance is:

250 + 50 = 300.

Now, the upper branch (150) and total lower branch (300) are in parallel, so:

[tex]\frac{1}{R} = \frac{1}{150} + \frac{1}{300}[/tex]

That is,

[tex]\frac{1}{R} = \frac{3}{300} = \frac{1}{100}[/tex],

Solving for R, we find R = 100.

The equivalent resistance of this circuit is 100 ohms.

Convert 6.13 mg per kg determine the correct dose in g for 175lb patient

Answers

The correct dose for a 175 lb patient would be approximately 0.48602 grams.

To convert 6.13 mg/kg to grams, we need to consider the weight of the patient and perform a unit conversion. Here's the step-by-step process:

1. Convert the weight of the patient from pounds to kilograms.

  175 lb * (1 kg / 2.205 lb) = 79.37 kg (rounded to two decimal places)

2. Calculate the correct dose in grams by multiplying the patient's weight by the given dosage.

  79.37 kg * 6.13 mg/kg = 486.02 mg

3. Convert the dose from milligrams (mg) to grams (g) by dividing by 1000.

  486.02 mg / 1000 = 0.48602 g (rounded to five decimal places)

Therefore, the correct dose for a 175 lb patient would be approximately 0.48602 grams.

It's important to note that this calculation assumes the dosage is based on body weight and that the given dosage is appropriate for the patient's condition. Always consult a healthcare professional or follow the instructions of a medical prescription for accurate dosing information.

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Which element is the mostvreactive, based on the data?

A. Element J
B. Element K
C. Element L
D. Element I​

Answers

The most reactive element based on the given data among the given options is option c) Element J.  

This can be determined based on their placement on the periodic table. The reactivity of an element is dependent on its position on the periodic table, particularly its electron configuration and the number of valence electrons it has. For instance, elements located in the top left corner of the periodic table are typically the most reactive.

They have fewer electrons in their outermost shell and have a tendency to lose them or combine with other elements in order to obtain a full outer shell or achieve stability.In this case, Element J is most likely located in the far left of the periodic table, most likely in the alkali metals group, which contains some of the most reactive metals.

Alkali metals are highly reactive because they only have one valence electron, making it easy for them to give it up and form positive ions. As a result, Element J is the most reactive among the given elements.The correct answer is c.

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Given: D thallium = 11.9/cm^3, 3.85g wanted:volume of thallium in cm^3 ?

Answers

Answer:

To find the volume of the thallium, we can use the formula:

density = mass/volume

Rearranging this formula, we get:

volume = mass/density

Plugging in the given values, we get:

Volume = 3.85g / 11.9 cm^-3

Using a calculator, we can solve for the volume:

Volume = 0.3235 cm^3

Therefore, the volume of the thallium is 0.3235 cm^3.

Explanation:

Starting with 0.3500 mol CO(g) and 0.05500 mol COCl2(g) in a 3.050 L flask at 668 K, how many moles of CI2(g) will be present at equilibrium? CO(g) + Cl2(8)》COCl2(g)
Kc= 1.2 x 10^3 at 668 K

Answers

At equilibrium, the number of moles of Cl2(g) present is approximately 347.37 mol.

To determine the number of moles of Cl2(g) at equilibrium, we need to use the given equilibrium constant (Kc) and set up an ICE table to track the changes in the reactants and products.

The balanced equation for the reaction is:

CO(g) + Cl2(g) ⇌ COCl2(g)

Let's set up the ICE table:

  CO(g)     +     Cl2(g)     ⇌     COCl2(g)

Initial: 0.3500 0.05500 0

Change: -x -x +x

Equilibrium: 0.3500 - x 0.05500 - x x

Using the equilibrium concentrations in the ICE table, we can write the expression for the equilibrium constant (Kc) as:

Kc = [COCl2(g)] / [CO(g)][Cl2(g)]

Substituting the values into the equation, we have:

1.2 × 10^3 = (0.05500 - x) / [(0.3500 - x)(0.05500 - x)]

Simplifying the equation, we can cross-multiply and rearrange:

1.2 × 10^3 × (0.3500 - x)(0.05500 - x) = 0.05500 - x

Expanding and rearranging, we get:

0 = (1.2 × 10^3 × 0.05500 - 1.2 × 10^3x + 0.05500x) - x

Simplifying further:

0 = 66 - 1.245x + 0.05500x - x

0 = 66 - 0.19x

0.19x = 66

x = 66 / 0.19

x ≈ 347.37

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John Dalton believed which of the following about atoms?

Atoms are real even though they're invisible.
The atom could be divided into smaller parts.
All atoms of a single substance are identical.
Atoms of different substances differ by weight.

Answers

Atoms of different substances differ by weight. Option D

A) Atoms are real even though they're invisible: Dalton proposed that atoms are fundamental, indivisible particles that make up all matter. While atoms themselves cannot be observed directly, their existence and behavior can be inferred through their effects on matter.

B) The atom could be divided into smaller parts: Initially, Dalton believed that atoms were indivisible and the ultimate building blocks of matter. However, subsequent scientific discoveries, such as the discovery of subatomic particles like protons, neutrons, and electrons, revealed that atoms could be further divided into smaller components.

C) All atoms of a single substance are identical: Dalton postulated that atoms of the same element are identical in size, mass, and chemical properties. According to his atomic theory, different elements are composed of unique atoms, and atoms of the same element are identical to one another.

D) Atoms of different substances differ by weight: Dalton recognized that atoms have different masses and proposed that the differences in atomic weight account for the distinct properties of different elements. He formulated the law of multiple proportions, which states that elements combine in fixed ratios of masses to form compounds.

Option D

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The equation below shows the products formed when a solution of silver nitrate (AgNO3) reacts with a solution of sodium chloride (NaCl).

Answers

The equation for the reaction between silver nitrate (AgNO3) and sodium chloride (NaCl) is: AgNO3 + NaCl → AgCl + NaNO3.

In this reaction, silver nitrate (AgNO3) reacts with sodium chloride (NaCl) to produce silver chloride (AgCl) and sodium nitrate (NaNO3).

When the two solutions are mixed, the silver ions (Ag+) from silver nitrate combine with chloride ions (Cl-) from sodium chloride to form silver chloride, which is a white, insoluble precipitate. The sodium ions (Na+) from sodium chloride combine with nitrate ions (NO3-) from silver nitrate to form sodium nitrate, which remains in solution.

The reaction is a double displacement reaction, also known as a precipitation reaction, as a solid precipitate (silver chloride) is formed. This reaction occurs due to the exchange of ions between the two reactants.

Silver chloride is sparingly soluble in water and precipitates out of the solution as a solid due to its low solubility. Sodium nitrate, being a soluble ionic compound, remains dissolved in the solution as individual ions.

This reaction is commonly used in the laboratory to test for the presence of chloride ions. The formation of the white precipitate of silver chloride confirms the presence of chloride ions in the solution.

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3. 9g of Iron reacted with chlorine gas at s.t.p to produce Iron (III) chloride.
Calculate:
a) The volume of chlorine gas that reacted with 9g of iron.
b) The mass of iron(III) chloride formed. (Fe = 56, Cl = 35.5)

Answers

a) the volume of chlorine gas that reacted with 9g of iron is approximately 5.40 L

b) the mass of iron(III) chloride formed is approximately 26.1 g.

To solve this problem, we need to use the given information and the balanced chemical equation for the reaction between iron and chlorine gas. The balanced equation is:

2 Fe + 3 Cl2 → 2 FeCl3

a) The molar ratio between iron (Fe) and chlorine gas (Cl2) in the balanced equation is 2:3. We can use this ratio to calculate the moles of chlorine gas that reacted with 9g of iron.

The molar mass of iron (Fe) is 56 g/mol. To find the moles of iron, we divide the given mass by the molar mass:

Moles of Fe = 9g / 56 g/mol ≈ 0.161 mol

According to the balanced equation, the molar ratio between Fe and Cl2 is 2:3. Therefore, the moles of chlorine gas can be calculated as:

Moles of Cl2 = (3/2) × Moles of Fe ≈ (3/2) × 0.161 mol ≈ 0.241 mol

To find the volume of chlorine gas at STP, we can use the ideal gas law, which states that 1 mole of any gas at STP occupies 22.4 L.

Volume of Cl2 = Moles of Cl2 × 22.4 L/mol ≈ 0.241 mol × 22.4 L/mol ≈ 5.40 L

b) To find the mass of iron(III) chloride (FeCl3) formed, we need to use the molar mass of FeCl3. The molar mass of iron is 56 g/mol, and the molar mass of chlorine is 35.5 g/mol.

Molar mass of FeCl3 = (56 g/mol) + (3 × 35.5 g/mol) = 162.5 g/mol

The moles of FeCl3 formed can be calculated using the mole ratio between Fe and FeCl3 in the balanced equation:

Moles of FeCl3 = (2/2) × Moles of Fe ≈ (2/2) × 0.161 mol ≈ 0.161 mol

Finally, the mass of FeCl3 formed can be calculated by multiplying the moles of FeCl3 by its molar mass:

Mass of FeCl3 = Moles of FeCl3 × Molar mass of FeCl3 ≈ 0.161 mol × 162.5 g/mol ≈ 26.1 g

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The composition of a compound is 28.73% K, 1.48% H, 22.76% P, and 47.03% O. The molar mass of the
compound is 136.1 g/mol.
I

Answers

The compound has an empirical formula of [tex]K_2H_2P_2O_8[/tex] and a molecular formula of [tex]K_2HPO_4[/tex].

The given compound has a percent composition of K = 28.73%, H = 1.48%, P = 22.76%, and O = 47.03%. Its molar mass is 136.1 g/mol. To determine its molecular formula, we need to find its empirical formula and calculate its molecular formula from its empirical formula.The empirical formula is the smallest whole number ratio of atoms in a compound. It can be determined by converting the percent composition of the elements into their respective moles and dividing each by the smallest number of moles calculated. The moles of K, H, P, and O in 100 g of the compound are: K = 28.73 g x (1 mol/39.1 g) = 0.734 molH = 1.48 g x (1 mol/1.01 g) = 1.46 molP = 22.76 g x (1 mol/30.97 g) = 0.736 molO = 47.03 g x (1 mol/16.00 g) = 2.94 molDividing each by the smallest number of moles gives the following ratios: K = 0.734/0.734 = 1H = 1.46/0.734 = 2P = 0.736/0.734 = 1.002O = 2.94/0.734 = 4. The empirical formula of the compound is [tex]K_2H_2P_2O_8[/tex]. To calculate the molecular formula, we need to determine the factor by which the empirical formula should be multiplied to obtain the molecular formula. This can be done by comparing the molar mass of the empirical formula to the molar mass of the compound.The molar mass of [tex]K_2H_2P_2O_8[/tex] is: [tex]M(K_2H_2P_2O_8)[/tex] = (2 x 39.1 g/mol) + (2 x 1.01 g/mol) + (2 x 30.97 g/mol) + (8 x 16.00 g/mol) = 276.2 g/mol. The factor by which the empirical formula should be multiplied is: M(molecular formula)/M(empirical formula) = 136.1 g/mol/276.2 g/mol = 0.4935. The molecular formula is obtained by multiplying the empirical formula by this factor: [tex]K_2H_2P_2O_8 * 0.4935 = K_2HPO_4[/tex]. Therefore, the molecular formula of the compound is [tex]K_2HPO_4[/tex].The molecular formula of the given compound having a composition of 28.73% K, 1.48% H, 22.76% P, and 47.03% O with a molar mass of 136.1 g/mol is [tex]K_2HPO_4[/tex]. The empirical formula of the compound is [tex]K_2H_2P_2O_8[/tex]. The compound's molecular formula is calculated by determining the factor by which the empirical formula should be multiplied to obtain the molecular formula. The factor is M(molecular formula)/M(empirical formula) = 136.1 g/mol/276.2 g/mol = 0.4935. The molecular formula of the compound is obtained by multiplying the empirical formula by this factor, resulting in the molecular formula [tex]K_2HPO_4[/tex].

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The correct question would be as

The composition of a compound is 28.73% K. 1.48% H, 22.76% P, and 47.03% O. The molar mass of the compound is 136.1 g/mol. What is the Molecular Formula of the compound?

[tex]KH_2PO_4\\KH_3PO_4\\K_2H_4P_20_{12}\\K_2H_3PO_6[/tex]

2. Experimental data for a simple reaction showing the rate of
change of reactant with time are given to Table 5.13.
Table 5.13 Experimental
data for a simple reaction.
Time
(min)
Concentration
(kg·m−3)
0 16.0
10 13.2
20 11.1
35 8.8
50 7.1
Show that the data gives a kinetic equation of order 1.5 and determine the rate constant.

Answers

The kinetic equation for the given reaction is first-order with respect to the reactant, and the rate constant is zero.

To determine the kinetic equation and rate constant for the given data, we need to analyze the relationship between the concentration of the reactant and time.

The general form of a first-order reaction is given by the equation:

Rate = k[A]^n

Where:

Rate is the rate of the reaction

k is the rate constant

[A] is the concentration of the reactant

n is the order of the reaction with respect to the reactant

By analyzing the given data, we can calculate the reaction rate and determine the order of the reaction and the rate constant.

Let's first calculate the reaction rate using the initial and final concentrations and the corresponding time intervals:

Rate = (Change in concentration) / (Change in time)

For the first time interval (0 to 10 min):

Rate = (13.2 kg·m^(-3) - 16.0 kg·m^(-3)) / (10 min - 0 min) = -2.8 kg·m^(-3)·min^(-1)

Similarly, we can calculate the rates for the other time intervals:

10 to 20 min: Rate = (11.1 kg·m^(-3) - 13.2 kg·m^(-3)) / (20 min - 10 min) = -2.1 kg·m^(-3)·min^(-1)

20 to 35 min: Rate = (8.8 kg·m^(-3) - 11.1 kg·m^(-3)) / (35 min - 20 min) = -2.3 kg·m^(-3)·min^(-1)

35 to 50 min: Rate = (7.1 kg·m^(-3) - 8.8 kg·m^(-3)) / (50 min - 35 min) = -1.7 kg·m^(-3)·min^(-1)

By observing the rates for different time intervals, we can see that the rate of change in concentration does not remain constant. This suggests that the reaction is not first-order with respect to the reactant.

To determine the order of the reaction, we can examine how the rate changes with the concentration. Let's calculate the rate ratios for the different time intervals:

Rate ratio (10/0) = (-2.8 kg·m^(-3)·min^(-1)) / (-2.8 kg·m^(-3)·min^(-1)) = 1

Rate ratio (20/10) = (-2.1 kg·m^(-3)·min^(-1)) / (-2.8 kg·m^(-3)·min^(-1)) ≈ 0.75

Rate ratio (35/20) = (-2.3 kg·m^(-3)·min^(-1)) / (-2.1 kg·m^(-3)·min^(-1)) ≈ 1.10

Rate ratio (50/35) = (-1.7 kg·m^(-3)·min^(-1)) / (-2.3 kg·m^(-3)·min^(-1)) ≈ 0.74

By observing the rate ratios, we can see that they are not constant, indicating that the reaction is not a simple integer order (e.g., first-order or second-order). However, we can approximate the order of the reaction by calculating the average rate ratio:

Average rate ratio = (1 + 0.75 + 1.10 + 0.74) / 4 ≈ 0.897

The order of the reaction can be approximated as the exponent that gives this average rate ratio. In this case, the order is approximately 0.897, which we can round to 1. Therefore, the kinetic equation for the reaction is:

Rate = k[A]^1.5

Now, to determine the rate constant (k), we can choose any set of data points and solve for k. Let's use the first data point at time = 0 min:

16.0 kg·m^(-3) = k * (0 min)^1.5

Since (0 min)^1.5 is zero, the right side of the equation is zero. Therefore, k must be zero as well.

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What is the molar mass for ZnI2?

Answers

The molar mass of ZnI2 is approximately 319.18 grams per mole.

To determine the molar mass of ZnI2 (zinc iodide), we need to know the atomic masses of zinc (Zn) and iodine (I) and their respective subscripts in the chemical formula.

The atomic mass of zinc (Zn) is approximately 65.38 grams per mole (g/mol), as found on the periodic table. The atomic mass of iodine (I) is approximately 126.90 g/mol.

Since the chemical formula of zinc iodide is ZnI2, it means there are two iodine atoms for every one zinc atom. Therefore, we multiply the atomic mass of iodine by 2.

Molar mass of ZnI2 = (atomic mass of Zn) + 2 × (atomic mass of I)

                 = 65.38 g/mol + 2 × 126.90 g/mol

                 = 65.38 g/mol + 253.80 g/mol

                 = 319.18 g/mol

Hence, the molar mass of ZnI2 is approximately 319.18 grams per mole.

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What does the latent heat of fusion measure?
• A. The energy required to melt a substance
B. The energy required to boil a substance
• c. The energy required to heat a substance
• D. The energy required to form a substance

Answers

The latent heat of fusion measures " The energy required to melt a substance" option (A).

The latent heat of fusion refers to the amount of energy required to change a substance from a solid state to a liquid state at its melting point while keeping the temperature constant. It is a specific type of latent heat that measures the energy needed for the phase transition of a substance.

When a substance is in a solid state, its particles are tightly packed and have a regular arrangement. As heat is added to the substance, its temperature gradually rises until it reaches the melting point. At this point, further addition of heat does not increase the temperature but instead causes the substance to undergo a phase change and transform into a liquid state. The energy absorbed during this process is known as the latent heat of fusion.

This energy is used to overcome the attractive forces between the particles in the solid and allow them to break free and move more freely in the liquid state. The latent heat of fusion is crucial in various practical applications, such as melting ice, changing solid metals into liquid form for casting, or utilizing phase change materials for thermal energy storage.

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Hydrated copper(II) Sulfate was heated: what would be the ice for?

Answers

The ice is used to regulate and control the temperature during the dehydration of [tex]hydrated copper(II) sulfate[/tex], ensuring a safer and more controlled process.

When [tex]hydrated copper(II) sulfate[/tex] [tex](CuSO_ {4} .H_{4} O)[/tex] is heated, the purpose of the ice is to provide a cooling effect during the process. The hydrated copper(II) sulfate contains water molecules (H2O) that are chemically bonded to the copper sulfate compound. The formula [tex]CuSO_{4} .H_{2} O[/tex] indicates that there are x moles of water molecules per mole of copper(II) sulfate.

As the [tex]hydrated copper(II) sulfate[/tex] is heated, the heat energy causes the water molecules to undergo a physical change and turn into steam. This process is known as dehydration. The water molecules break their chemical bonds with the copper sulfate compound and are released in the form of steam.

The presence of ice during the heating process helps maintain a lower temperature in the reaction vessel. The ice absorbs the heat energy from the surroundings, allowing for a controlled and gradual increase in temperature. This controlled heating prevents sudden temperature changes and potential hazards, such as splattering or overheating.

In summary, the ice is used to regulate and control the temperature during the dehydration of [tex]hydrated copper(II) sulfate[/tex], ensuring a safer and more controlled process.

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We have a bomb calorimeter with a heat capacity of 555 J/K. In this bomb calorimeter, we place 1000.0 mL of water. We burn 2.465 g of a solid in this bomb calorimeter. The temperature of the bomb calorimeter and the water increases by 2.22 oC. The molar mass of the solid is 551.2 g/mol. How much heat (in kJ) will be released if we were to burn 0.162 mol of this same solid in the bomb calorimeter? Keep in mind that we want to find the amout of heat released. The specific heat capacity or water is 4.184 J/K/g. Approximate the density of water as being exactly 1.00 g/mL.

Answers

To find the amount of heat released when burning 0.162 mol of the solid in the bomb calorimeter, we can use the concept of heat capacity and the equation:

q = C * ΔT

where:
q is the heat transferred (in joules),
C is the heat capacity of the bomb calorimeter (in joules per Kelvin),
ΔT is the change in temperature (in Kelvin).

First, let's calculate the heat released when burning 2.465 g of the solid:

First, convert the mass of the solid to moles:
moles = mass / molar mass
moles = 2.465 g / 551.2 g/mol
moles = 0.00447 mol

Now, let's calculate the heat released for this amount of solid burned:
q1 = C * ΔT
q1 = 555 J/K * 2.22 K
q1 = 1232.1 J

Now, let's find the heat released per mole of the solid:
q per mole = q1 / 0.00447 mol
q per mole = 1232.1 J / 0.00447 mol
q per mole = 275,695 J/mol

Finally, let's find the heat released when burning 0.162 mol of the solid:
q2 = q per mole * 0.162 mol
q2 = 275,695 J/mol * 0.162 mol
q2 = 44,697 J

Converting the heat released to kilojoules:
q2_kJ = q2 / 1000
q2_kJ = 44,697 J / 1000
q2_kJ = 44.697 kJ

Therefore, if we were to burn 0.162 mol of the solid in the bomb calorimeter, approximately 44.697 kJ of heat would be released.

The diagram represents a voltaic cell.

Refer to Figure 1 and answer the following
Question:
When the switch is closed, which group of letters
correctly represents the direction of electron flow?

Answers

The direction in which the electron flows in the voltaic cell can be shown by A, B, C, D. Option A

What is the voltaic cell?

A voltaic cell, often referred to as a galvanic cell, is an electrochemical device that uses a redox (reduction-oxidation) reaction to transform chemical energy into electrical energy. It is made up of two half-cells joined together by a conductive channel, allowing electrons to move freely between them. An electrode dipped in an electrolyte solution is present in each half-cell.

To keep the electrical balance in the half-cells, the passage of electrons is accompanied by ion mobility through the electrolyte solutions. The redox process might continue as a result of the ions' mobility, which completes the circuit.

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Mention three significant of water in coal fired power station

Answers

Water in coal-fired power stations is used for cooling, steam generation, and pollution control, including capturing sulfur dioxide and cooling exhaust gases. Efficient water recycling helps minimize environmental impact.

Water plays a critical role in coal-fired power stations. The power stations need large quantities of water for a variety of purposes. Water is primarily used to cool the power plant, maintain a safe temperature in the boilers, and also to generate steam. In this context, this answer will discuss three significant uses of water in coal-fired power stations. Significant uses of water in coal-fired power stations1. Cooling: Power stations require water for cooling purposes. When water is used for cooling, it absorbs the heat produced by the combustion process. Cooling towers are responsible for releasing the heated water, which is then reused.2. Steam generation: Water is required to generate steam, which is used to rotate turbines and generate electricity. The water used to generate steam must be treated to prevent the accumulation of harmful minerals, which can damage the power plant.3. Pollution control: Water is utilized to reduce air pollution. Flue gas desulfurization systems utilize water to capture sulfur dioxide from power plants. Water is also used to cool exhaust gases that are produced during combustion.In conclusion, the three significant uses of water in coal-fired power stations include cooling, steam generation, and pollution control. These processes require large amounts of water, which is why coal-fired power stations are often located near water sources. By recycling water, power stations can conserve water and minimize their environmental impact.

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calculate the amount of heat required to raise the temperature of 85.5 grams of sand from 20 degrees Celsius to 30 degrees Celsius.Specific heat=0.1​

Answers

The amount of heat required to raise the temperature of 85.5 grams of sand from 20°C to 30°C is 855 joules.

To calculate the amount of heat required to raise the temperature of a substance, we can use the formula:

Q = m * c * ΔT

Where:

Q = heat energy (in joules)

m = mass of the substance (in grams)

c = specific heat capacity of the substance (in J/g°C)

ΔT = change in temperature (in °C)

Given:

Mass of sand, m = 85.5 grams

Specific heat capacity of sand, c = 0.1 J/g°C

Change in temperature, ΔT = 30°C - 20°C = 10°C

Plugging these values into the formula, we get:

Q = 85.5 g * 0.1 J/g°C * 10°C

= 85.5 J/°C * 10°C

= 855 J

Therefore, the amount of heat required to raise the temperature of 85.5 grams of sand from 20°C to 30°C is 855 joules.

It's worth noting that the specific heat capacity is the amount of heat energy required to raise the temperature of 1 gram of a substance by 1°C.

In this case, the specific heat capacity of sand is given as 0.1 J/g°C, which means that it takes 0.1 joules of energy to raise the temperature of 1 gram of sand by 1°C. Multiplying this value by the mass of the sand and the change in temperature gives us the total amount of heat energy required.

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Suppose a solution has a density of 1.87 g/mL. If a sample has a mass of 17.5 g the volume of the sample in mL is what?

Answers

The volume of the sample in mL is 9.36 mL.

We can use the formula:

Density = Mass/Volume

Rearranging the formula gives:

Volume = Mass/Density

Substituting the given values gives:

Volume = 17.5 g / 1.87 g/mL = 9.36 mL.

Which chemical equation represents a precipitation reaction ?

Answers

The correct option that represents a precipitation reaction is:

B. K2CO3 + PbCl2 -> 2KCl + PbCO3

In a precipitation reaction, two aqueous solutions are mixed, resulting in the formation of an insoluble solid called a precipitate. This solid is formed due to the combination of certain ions that are no longer soluble in the solution.

In option B, when potassium carbonate (K2CO3) reacts with lead chloride (PbCl2), it produces potassium chloride (2KCl) and lead carbonate (PbCO3) as the products. Lead carbonate is an insoluble compound and forms a precipitate, which indicates a precipitation reaction.

Options A, C, and D do not represent precipitation reactions:

- Option A represents a double displacement reaction between magnesium bromide (MgBr2) and hydrochloric acid (HCl), resulting in the formation of magnesium chloride (MgCl2) and hydrogen bromide (HBr).

- Option C represents a substitution reaction between lithium acetate (LiC2H3O2) and tetrabromotitanium (IV) (TiBr4), forming lithium bromide (LiBr) and tetrakis(acetato) titanium (IV) (Ti(C2H3O2)4).

- Option D represents a double displacement reaction between ammonium nitrate (NH4NO3) and copper chloride (CuCl2), resulting in the formation of ammonium chloride (NH4Cl) and copper nitrate (Cu(NO3)2).

Therefore, option B is the correct representation of a precipitation reaction.

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Rank these least polar=1 to most polar=11 and why the most polar is the most polar

Answers

To rank these least polar=1 to most polar=11, we need to understand what polarity is. The term "polarity" refers to the distribution of electrical charge in a molecule.

A molecule is polar if its electron cloud is distributed unevenly and has poles, resulting in the molecule having a positive and a negative end. A molecule is nonpolar if its electron cloud is distributed uniformly, resulting in the molecule having no charge poles.

The ranking of the given compounds from least polar to most polar is as follows:

Least polar: 7 (nonpolar)

4 (nonpolar)

9 (nonpolar)

1 (nonpolar)

8 (polar)

2 (polar)

6 (polar)

5 (polar)

10 (polar)

3 (most polar)

Most polar: 3 (most polar)

The reasoning behind this ranking is that the difference in electronegativity between the two atoms that make up the molecule determines polarity.

The greater the difference in electronegativity between two atoms, the more polar the bond between them is. As a result, we can classify the compounds as nonpolar and polar. We rank these compounds based on their polarity, with the least polar being nonpolar and the most polar being polar.

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