There are 15.4 equivalents of chloride ion present in the solution
To calculate the number of equivalents per mole of chloride ionWe need to multiply the total number of moles of chloride ion in the solution by the number of equivalents.
The molar mass of NaCl is 58.44 g/mol, so 3.5 mol of NaCl contains :
3.5 mol NaCl x 2 mol Cl⁻/1 mol NaCl = 7 mol Cl⁻
Similarly, the molar mass of MgCl₂ is 95.21 g/mol, so 4.2 mol of MgCl₂ contains:
4.2 mol MgCl₂ x 2 mol Cl⁻/1 mol MgCl₂ = 8.4 mol Cl⁻
Therefore, the total number of moles of chloride ion in the solution is:
7 mol Cl⁻ + 8.4 mol Cl⁻ = 15.4 mol Cl⁻
By dividing the total number of moles by the number of equivalents per mole, we can finally determine how many equivalents of the chloride ion there are. There is one equivalent of the chloride ion per mole since it has a valency of -1.
15.4 mol Cl⁻ x 1 eq/mol = 15.4 eq
So there are 15.4 equivalents of chloride ion present in the solution.
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Silver chloride, AgCl, is a sparingly soluble solid. Answer the following questions about a saturated solution prepared by placing solid silver chloride in a 2.45 10-5 M NaCl(aq) solution. At some temperature, the silver ion concentration, [Ag+], was found to be 5.36 10-6 M.
(a) What is the concentration of chloride ions, [Cl − ], in the resulting solution?
The solubility of silver chloride (AgCl) can be represented by the following equilibrium equation:
AgCl(s) ⇌ Ag+(aq) + Cl-(aq)
In a saturated solution of AgCl, the concentration of Ag+ ions is equal to the solubility product constant (Ksp) for AgCl at that temperature. Since the concentration of Ag+ ions in the solution is given as 5.36 x 10^-6 M, we can write:
[Ag+] = 5.36 x 10^-6 M
According to the stoichiometry of the equilibrium equation, the concentration of chloride ions ([Cl-]) is also equal to the concentration of Ag+ ions, as one mole of AgCl dissociates to yield one mole of Ag+ ions and one mole of Cl- ions. Therefore:
[Cl-] = 5.36 x 10^-6 M
So, the concentration of chloride ions in the resulting solution is 5.36 x 10^-6 M.
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Describe the intermolecular forces that must be overcome to convert each of the following from a liquid or solid to a gas.
P2O5 and HI
For P₂O₅ the intermolecular forces such as van der Waals forces, dipole-dipole interactions, and hydrogen bonding must be overcome.
For HI the intermolecular forces that must be overcome are as van der Waals forces, dipole-dipole interactions, and hydrogen bonding.
What are the intermolecular forces that must be overcome?P₂O₅ is a covalent compound and it is solid. To convert P₂O₅ from a solid to a gas, intermolecular forces such as van der Waals forces, dipole-dipole interactions, and hydrogen bonding must be overcome.
HI is a covalent compound that is a gas at room temperature and pressure. To convert HI from a liquid to a gas, intermolecular forces such as van der Waals forces, dipole-dipole interactions, and hydrogen bonding must be overcome.
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What is the electron configuration for magnesium (Mg)?
O A. 1s²2s²2p²356
B. 15²25²3s23p6
C. 3s²3p 3d
D. 1s²2s²2p63s²
Answer:
D is correct.(1s22s22p63s2)
A titration setup was used to determine the unknown molar concentration of a solution of NaOH. A1.2 M HCl solution was used as the
titration standard. The following data were collected.
Trial 1
Amount of HCI
Standard Used 10.0 mL
0.0 mL
Initial NaOH
Buret Reading
Final NaOH
Buret Reading 12.2 mL
Trial 2
10.0 mL
12.2 mL
23.2 mL
Trial 3 Trial 4
10.0 mL 10.0 mL
23.2 mL 35.2 mL
35.2 mL 47.7 mL
79) Calculate the volume of NaOH solution used to neutralize 10.0 ml. of the standard HCl solution in trial 3 in the given diagram.
[Show your work.]
If an aqueous solution is 5.321m, which of the following statements is incorrect?
A) Freezing point of solution will lower by 10 C
B) Boiling point of solution will increase by 2.72 C
C) Boiling point of solution will be 100 C
D) Osmotic pressure of solution will be higher than water
Boiling point of solution will be 100 C. The incorrect statement is C)
What is aqueous solution ?An aqueous solution is one in which water serves as the solvent. One or more substances are dissolved in water to create such a solution, and the water molecules surround and separate the individual solute particles to create a homogeneous mixture.
Therefore, A solvent's boiling point and freezing point change when a solute is dissolved in it, respectively. Boiling point elevation and freezing point depression are two terms used to describe this occurrence. The concentration of the solute determines how much of an impact it has.
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Iron pyrite (FeS2) is the form in which much of
the sulfur exists in coal. In the combustion of
coal, oxygen reacts with iron pyrite to produce
iron(III) oxide and sulfur dioxide, which is a
major source of air pollution and a substantial
contributor to acid rain. What mass of Fe2O3
is produced from 74 L of oxygen at 2.97 atm
and 161◦C with an excess of iron pyrite?
Answer in units of g
The mass of Fe₂O₃ produced is 101.9 g.
How to calculate mass ?The balanced chemical equation for the combustion of iron pyrite is:
4FeS₂(s) + 11O₂(g) → 2Fe₂O3(s) + 8SO₂(g)
From the equation, 11 moles of oxygen are required to produce 2 moles of Fe₂O₃. Convert the given volume of oxygen to moles:
n(O2) = PV/RT = (2.97 atm)(74 L)/(0.0821 L·atm/mol·K)(161 + 273 K) = 3.51 mol
Since the reaction requires 11 moles of O₂ for every 2 moles of Fe₂O₃, calculate the moles of Fe₂O₃ produced:
n(Fe₂O₃) = (2/11) × n(O₂) = (2/11) × 3.51 mol = 0.638 mol
Finally, use the molar mass of Fe₂O₃ to convert moles to grams:
m(Fe₂O₃) = n(Fe₂O₃) × M(Fe₂O₃) = 0.638 mol × 159.69 g/mol = 101.9 g
Therefore, the mass of Fe₂O₃ produced is 101.9 g.
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We wish to determine the mass of Mg required to react completely with 250mL of 1.0 M HCI. HCI reacts with Mg according to the equation below.
2HCl(aq) + Mg(s) → MgCl₂(aq) + H₂(g)
How many moles of HCI are present in 250. mL of 1.0 M HCl?
There are 0.25 moles of HCl present in 250 mL of 1.0 M HCl.
We have to calculate the number of moles of HCl present in some mL of 1.0M HCl. A mole is defined as the amount of substance in a system that contains as many elementary entities as there are atoms in 0.012 kg of carbon 12. We represent mole by the symbol 'mol'. Now, we will see how to calculate the number of moles.
We can calculate the number of moles of a substance using the following expression;
Molarity = no of moles of an element/volume
According to this question, we were given 250. mL of 1.0 M HCl. The number of moles will be calculated by the formula as follows;
no of moles of HCl = 0.250L × 1.0M
no of moles of HCl = 0.250 moles.
Therefore, 0.25 moles are present in 250 mL of 1.0 M HCl.
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A 7.95 L
container holds a mixture of two gases at 25 °C.
The partial pressures of gas A and gas B, respectively, are 0.352 atm
and 0.715 atm.
If 0.240 mol
of a third gas is added with no change in volume or temperature, what will the total pressure become?
Calculate the cell potential for the galvanic cell in which the given reaction occurs at 25 °C, given that [Ti2+]=0.00140 M and [Au3+]=0.887 M .
3Ti(s)+2Au3+(aq)↽−−⇀3Ti2+(aq)+2Au(s)
Under the specified conditions, the cell potential of the given galvanic cell is 3.11 V.
How to determine cell potential?The standard reduction potentials for the half-reactions involved in the cell reaction are:
Ti²⁺(aq) + 2e- ⇆ Ti(s) E° = -1.63 V
Au³⁺(aq) + 3e- ⇆ Au(s) E° = +1.50 V
The cell potential (Ecell) is given by:
Ecell = E°cathode - E°anode
where E°cathode = standard reduction potential of the cathode (reduction half-reaction) and E°anode = standard reduction potential of the anode (oxidation half-reaction).
In this case, Ti²⁺ is oxidized (anode) and Au³⁺ is reduced (cathode). Therefore:
E°anode = -1.63 V
E°cathode = +1.50 V
So, Ecell = +1.50 V - (-1.63 V) = +3.13 V
The Nernst equation can be used to calculate the cell potential (Ecell) under non-standard conditions:
Ecell = E°cell - (RT/nF) ln(Q)
where R = gas constant (8.314 J/(molK)), T = temperature in Kelvin (25 °C = 298 K), n = number of electrons transferred in the balanced equation (3 in this case), F = Faraday constant (96,485 C/mol), and Q = reaction quotient.
For the given concentrations:
[Ti²⁺] = 0.00140 M
[Au³⁺] = 0.887 M
The reaction quotient Q can be written as:
Q = ([Ti²⁺]³/[Au³⁺]²)
Substituting the values into the Nernst equation:
Ecell = E°cell - (RT/nF) ln([Ti²⁺]³/[Au³⁺]²)
Ecell = 3.13 V - (8.314 J/(molK) × 298 K / (3 × 96,485 C/mol)) ln(0.00140³/0.887²)
Ecell = 3.13 V - 0.0217 V
Ecell = 3.11 V
Therefore, the cell potential for the given galvanic cell under the given conditions is 3.11 V.
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What is the molar mass of potassium hydroxide, KOH?
Answer:
56.11 g/mol
Explanation:
To determine the molar mass of potassium hydroxide, we need to find the atomic mass of each element in the compound and add them up.
The atomic mass of potassium (K) is 39.10 g/mol, the atomic mass of oxygen (O) is 16.00 g/mol, and the atomic mass of hydrogen (H) is 1.01 g/mol.
So, the molar mass of potassium hydroxide (KOH) is:
Molar mass of K = 39.10 g/mol
Molar mass of O = 16.00 g/mol
Molar mass of H = 1.01 g/mol
Molar mass of KOH = Molar mass of K + Molar mass of O + Molar mass of H
= 39.10 g/mol + 16.00 g/mol + 1.01 g/mol
= 56.11 g/mol
Therefore, the molar mass of potassium hydroxide (KOH) is 56.11 g/mol.
a student mixed 20 grams of salt into a beaker with 200 milliliters of warm water. then, the student set the cup of saltwater on a windowsill undisturbed for one week. what changes did the student observe? include what happened when salt was mixed with warm water and what most likely happened to the saltwater after one week.
Answer:
Water molecules pull the sodium and chloride ions apart, breaking the ionic bond that held them together. After the salt compounds are pulled apart, the sodium and chloride atoms are surrounded by water molecules, as this diagram shows. Once this happens, the salt is dissolved, resulting in a homogeneous solution.
Explanation:
Why are leaves green
Answer:
Leaves are green due to the presence of an organelle chloroplast (in abundance) which contains the pigment chlorophyll
Explanation:
Now saying chlorophyll pigment is a green pigment might be slightly incorrect. The two famous types (Chlorophyll a, Chlorophyll b) only absorb red and blue light from the atmosphere and reflect green light hence giving the pigment a green appearance and lastly giving the leaves a green color too
Answer:
Chlorophyll
Explanation:
Plants are often seen as green to the human eye due to the presence of chlorophyll, which is the primary pigment used in photosynthesis. Chlorophyll absorbs light in the red and blue-violet parts of the spectrum, but reflects or transmits green light, resulting in the characteristic green color of leaves.
As the hour of her new job approached, Emma could feel her excitement blank
As the hour of her new job approached, Emma could feel her excitement peak.
What word can replace intensify ?"Peak" is a synonym to "intensify" in this context because it means to reach the highest point or level of something. In the given passage, Emma's excitement is growing stronger and stronger as the time for her volunteer job approaches.
When her excitement "peaks," it means that it has reached the highest point of intensity, just like when something is intensified, it becomes stronger or more intense.
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The enthalpy combustion of ethanol is -1430 kJ/mol. Determine heat given off from the combustion of 1 dm³ of ethanol. Given density of ethanol is 0.79 gcm³. (molar mass ethanol = 46 g/mol)
Answer:
The enthalpy of combustion of ethanol is -1430 kJ/mol, which means that for every mole of ethanol that is burned, 1430 kJ of heat is released.
To determine the amount of heat given off from the combustion of 1 dm³ of ethanol, we need to first calculate the number of moles of ethanol in 1 dm³.
1 dm³ is equivalent to 1000 cm³. Since the density of ethanol is 0.79 g/cm³, the mass of 1 dm³ of ethanol can be calculated as:
mass = density x volume
mass = 0.79 g/cm³ x 1000 cm³
mass = 790 g
To convert this mass to moles, we need to divide by the molar mass of ethanol:
moles = mass / molar mass
moles = 790 g / 46 g/mol
moles = 17.17 mol
Therefore, 1 dm³ of ethanol contains 17.17 moles of ethanol.
To calculate the heat given off from the combustion of 1 dm³ of ethanol, we can use the following equation:
heat = enthalpy of combustion x moles of ethanol
heat = -1430 kJ/mol x 17.17 mol
heat = -24,551 kJ
Therefore, the heat given off from the combustion of 1 dm³ of ethanol is -24,551 kJ, or approximately 24,551 kJ of heat is released.
For the reaction:
S8(s) + 8 O2(g)⟶8 SO2(g) ΔH = –2368 kJ
How much heat is evolved when 25.0 moles of sulfur is burned in excess oxygen?
The amount of heat evolved when 25 moles of Sulfur is burned in excess oxygen is -74000 kJ.
The balanced reaction is given that is:
[tex]S_8(s) + 8 O_2(g) \rightarrow 8 SO_2(g)[/tex]
We can see that 1 mole of [tex]S_8[/tex] reacts with 8 moles of [tex]O_2[/tex] to produce 8 moles of [tex]So_2[/tex].
If 25.0 moles of [tex]S_8[/tex] reacts with excess Oxygen, then the amount of [tex]O_2[/tex] which is required in the reaction will be:
8 moles [tex]O_2[/tex] / 1 mole S8 × 25.0 moles S8 = 200 moles [tex]O_2[/tex]
We can use the enthalpy change and calculate the amount of heat evolved:
[tex]\Delta H[/tex] = -2368 kJ/ 8 moles [tex]SO_2[/tex]
The heat evolved = [tex]\Delta H[/tex] × moles of [tex]SO_2[/tex] produced
Moles of [tex]SO_2[/tex] produced = 8 moles [tex]SO_2[/tex] / 1 mole [tex]S_8[/tex] × 25.0 moles [tex]S_8[/tex]
= 200 moles [tex]SO_2[/tex].
Therefore, Heat evolved= -2368 kJ/ 8 moles [tex]SO_2[/tex] × 200 moles [tex]SO_2[/tex]
= -74000 kJ
The amount of heat evolved when 25 moles of Sulfur is burned in excess oxygen is -74000 kJ, the negative sign here indicates that the reaction is exothermic.
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A rock is placed on a scale and gives a reading of 76.89 grams. The rock is then placed in a graduated cylinder with 63.12 mL of water, the water rises to a volume of 73.54mL What is the density of the rock? (you answer must have a total of 2 decimals)
What volume of oxygen gas can be collected
at 1.05 atm pressure and 44.0◦C when 42.5 g
of KClO3 decompose by heating, according to
the following equation?
2 KClO3(s) ∆
−−−−→
MnO2
2 KCl(s) + 3 O2(g)
Answer in units of L.
005 1.0 points
The volume of oxygen gas, O₂ collected at 1.05 atm pressure and 44.0 °C when 42.5 g of KClO₃ decomposed is 13.01 L
How do i determine the volume of oxygen gas collected?We shall begin by obtaining the mole in 42.5 g of KClO₃. Details below:
Mass of KClO₃ = 42.5 g Molar mass of KClO₃ = 122.5 g/mol Mole of KClO₃ =?Mole = mass / molar mass
Mole of CaC₂ = 42.5 / 122.5
Mole of CaC₂ = 0.35 mole
Next, we shall determine the mole of oxygen gas, O₂. produced. Details below:
2KClO₃ -> 2KCl + 3O₂
From the balanced equation above,
2 moles of KClO₃ decomposed to produced 3 mole of O₂
Therefore,
0.35 mole of KClO₃ will decompose to produce = (0.35 × 3) / 2 = 0.525 mole O₂
Finally, we shall determine the volume of oxygen gas, O₂ collected. Details below:
Pressure (P) = 1.05 atmTemperature (T) = 44 °C = 44 + 273 = 317 KGas constant (R) = 0.0821 atm.L/mol KNumber of mole (n) = 0.525 moleVolume of gas (V) =?PV = nRT
1.05 × V = 0.525 × 0.0821 × 317
Divide both sides by 1.05
V = (0.525 × 0.0821 × 317) / 1.05
Volume of oxygen gas = 13.01 L
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The change in enthalpy (AH, ) for a reaction is -25.8 kJ mol.
The equilibrium constant for the reaction is 1.4 × 103 at 298 K.
What is the equilibrium constant for the reaction at 655 K?
The equilibrium constant for the reaction at 655 K is [tex]e^{6.96}[/tex] ≈ 1.05 × 10^3.
The equilibrium constant (K) for a reaction is related to the change in Gibbs free energy (ΔG) through the equation:
ΔG = -RTlnK
where R is the gas constant, T is the temperature in kelvin, and ln is the natural logarithm. Since ΔG and ΔH (the change in enthalpy) are related by the equation:
ΔG = ΔH - TΔS
where ΔS is the change in entropy, we can rearrange the first equation to get:
lnK = -ΔH ÷ RT + ΔS ÷ R
At 298 K, we can use the given values of ΔH and K to solve for ΔS:
lnK = -ΔH ÷ RT + ΔS ÷ R
ln(1.4 × 10³) = (-(-25.8 × 10³ J/mol) ÷ (8.314 J/mol K × 298 K)) + ΔS ÷ 8.314 J/mol K
ΔS = 78.2 J/mol K
Now we can use the equation above to solve for lnK at 655 K, using the same value of ΔH and the newly calculated value of ΔS:
lnK = -ΔH ÷ RT + ΔS ÷ R
lnK = -(-25.8 × 10³ J/mol) ÷ (8.314 J/mol K × 655 K) + (78.2 J/mol K) ÷ 8.314 J/mol K
lnK = 6.96
e ≈ 1.05 × 10³
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diagram of reaction of water,oxygen,acids
When water and oxygen react in the presence of an acid, the oxygen can oxidize the acid to produce a compound and release hydrogen ions.
Reaction:
The reaction is as follows and it's diagram mentioned below.
Acid + Oxygen + Water → Compound + Hydrogen ions
if we take the acid hydrochloric acid (HCl), the reaction with oxygen and water can produce the compound chlorine dioxide ([tex]ClO_{2}[/tex]) and hydrogen ions ([tex]H^{+}[/tex]):
2 HCl + [tex]O_{2}[/tex] + [tex]H_{2}O[/tex] → 2 [tex]ClO_{2}[/tex] + 4 [tex]H^{+}[/tex]
This type of reaction is known as an oxidation-reduction reaction or a redox reaction, where one species is oxidized (loses electrons) while the other is reduced (gains electrons).
What is redox reaction?
A redox reaction, also known as an oxidation-reduction reaction, is a type of chemical reaction in which there is a transfer of electrons between two species. One species undergoes oxidation, meaning it loses electrons, while the other species undergoes reduction, meaning it gains electrons.
Redox reactions are fundamental to many processes in nature and technology, including photosynthesis, respiration, corrosion, and energy production in batteries and fuel cells. They are also important in many industrial processes, such as the production of metals, chemicals, and pharmaceuticals.
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What is the volume of a 1.0 M solution that has 4.0 moles of solute?
The volume of a 1.0 M solution that has 4.0 moles of solute is 4.0 liters.
What is mole ?A mole is a unit of measurement used in chemistry to represent the quantity of a chemical.
We can use the following formula to get the volume of a 1.0 M solution containing 4.0 moles of solute:
moles of solute = molarity x volume of solution
To determine the volume of the solution, we can rearrange this formula as follows:
Volume of solution = molarity / moles of solute.
By entering the specified values, we obtain:
4.0 moles / 1.0 M is the solution's volume.
Solution volume = 4.0 L
Therefore, the volume of a 1.0 M solution that has 4.0 moles of solute is 4.0 liters.
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What will happen when pressure on a reactant mixture at equilibrium and with fewer moles on the reactant side is increased
when pressure of the reactant mixture at the equilibrium and with the fewer moles in reactant side will be increased and the equilibrium will be shift to the side in the reaction where the fewer moles of the gas.
According to the Le Chartelier, when the reaction is in the equilibrium phase and the one of the constraints which will affect the rate of the reactions, and the equilibrium will be shift to the cancel out this effect that the constraint had.
Therefore, If the pressure of the system or the reaction is in the equilibrium is change, the equilibrium of the reaction will be change that is depending on the side of the reaction with the highest number of the molecules.
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A solution of thickness 3cm transmits 30%. calculate the concentration of the solution. E= 400dm/mol/cm
The concentration of the solution is 0.000435 mol/dm³.
What is the concentration of the solution?The concentration of a solution is calculated as follows;
Concentration = (Absorbance) / (Molar absorptivity x path length)
the path length = 3cm
the molar absorptivity (E) = 400 dm/mol/cm.
if the solution transmits 30% of the light, it absorbs 70% of the incident light.
Absorbance = log (1/Transmittance)
Absorbance = log (1/0.3)
Absorbance = 0.523
Concentration = (0.523) / (400 dm/mol/cm x 3 cm)
= 0.000435 mol/dm³
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A sample of gas is contained in a 245 mL flask at a temperature of 23.5°C. The gas pressure is 37.8 mm Hg. The gas is moved to a new flask, which is then immersed in ice water, and which has a volume of 54 mL. What is the pressure of the gas in the smaller flask at the new temperature?
We can use the combined gas law to solve this problem:
(P1V1/T1) = (P2V2/T2)
where P1, V1, and T1 are the initial pressure, volume, and temperature, respectively, and P2, V2, and T2 are the final pressure, volume, and temperature, respectively.
We are given that the initial pressure is P1 = 37.8 mm Hg and the initial volume is V1 = 245 mL. The initial temperature is T1 = 23.5°C, which we need to convert to Kelvin by adding 273.15:
T1 = 23.5°C + 273.15 = 296.65 K
We are also given that the final volume is V2 = 54 mL, and the final temperature is the temperature of the ice water, which is 0°C or 273.15 K.
Now we can solve for the final pressure, P2:
(P1V1/T1) = (P2V2/T2)
P2 = (P1V1T2) / (V2T1)
P2 = (37.8 mm Hg * 245 mL * 273.15 K) / (54 mL * 296.65 K)
P2 = 24.4 mm Hg
Therefore, the pressure of the gas in the smaller flask at the new temperature is 24.4 mm Hg.
What is the limiting reagent in the reaction of 0.150 g of salicylic acid with 0.350 mL of acetic anhydride (d=1.082 g/mL)? Show your work.
The limiting reagent for the reaction between 0.150 g of salicylic acid and 0.350 mL of acetic anhydride is salicylic acid, C₇H₆O₃
How do i determine the limiting reagent?First, we shall determine the mass of the acetic anhydride. Details below:
Volume of acetic anhydride = 0.350Density of acetic anhydride = 1.082 g/mLMass of acetic anhydride =?Mass = density × volume
Mass of acetic anhydride, C₄H₆O₃ = 1.082 × 0.350
Mass of acetic anhydride, C₄H₆O₃ = 0.3787 g
Finally, we shall determine the limiting reagent. Details below:
C₇H₆O₃ + C₄H₆O₃ -> C₉H₈O₄ + CH₃COOH
Molar mass of C₇H₆O₃ = 138.121 g/molMass of C₇H₆O₃ from the balanced equation = 1 × 138.121 = 138.121 g Molar mass of C₄H₆O₃ = 102.09 g/molMass of C₄H₆O₃ from the balanced equation = 1 × 102.09 = 102.09 gFrom the balanced equation above,
138.121 g of C₇H₆O₃ reacted with 102.09 g of C₄H₆O₃
Therefore,
0.150 g of C₇H₆O₃ will react with = (0.150 × 102.09) / 138.121 = 0.11089 g of C₄H₆O₃
We can see from the above that only 0.11089 g of acetic anhydride, C₄H₆O₃ out of 0.3787 g is needed to react with 0.150 g of salicylic acid, C₇H₆O₃
Thus, the limiting reagent is salicylic acid, C₇H₆O₃
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Using the equations
N₂ (g) + O₂ (g) → 2 NO (g) ∆H° = 180.6 kJ/mol
N₂ (g) + 3 H₂ (g) → 2 NH₃ (g) ∆H° = -91.8 kJ/mol
2 H₂ (g) + O₂ (g) → 2 H₂O (g) ∆H° = -483.7 kJ/mol
Determine the molar enthalpy (in kJ/mol) for the reaction
4 NH₃ (g) + 5 O₂ (g) → 4 NO (g) + 6 H₂O (g).
The molar enthalpy for the reaction 4 NH₃ (g) + 5 O₂ (g) → 4 NO (g) + 6 H₂O (g) is 266.4 kJ/mol.
What is the molar enthalpy for the reaction?The molar enthalpy is determined from Hess's law as follows:
Equation 1 x2:
2 N₂ (g) + 2 O₂ (g) → 4 NO (g) ∆H° = 361.2 kJ/mol
Equation 3 x3, :
6 H₂ (g) + 3 O₂ (g) → 6 H₂O (g) ∆H° = -1451.1 kJ/mol
Equation 2 x -4:
-8 N₂ (g) - 12 H₂ (g) → -8 NH₃ (g) ∆H° = 367.2 kJ/mol
Adding the equations together:
-6 N₂ (g) - 6 H₂ (g) + 5 O₂ (g) → 4 NO (g) + 6 H₂O (g) - 8 NH₃ (g) ∆H° = 266.3 kJ/mol
Multiplying the equation above by -1/2:
3 N₂ (g) + 3 H₂ (g) - 5/2 O₂ (g) → -2 NO (g) - 3 H₂O (g) + 4 NH₃ (g) ∆H° = -133.2 kJ/mol
Multiplying the above equation by -2:
4 NH₃ (g) + 5 O₂ (g) → 4 NO (g) + 6 H₂O (g) ∆H° = 266.4 kJ/mol
This is the molar enthalpy of the given reaction
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The following first-order reaction occurs in CCL4(l) at 45°C: N2O5》N2O4+1÷2O2. The rate consast is k=6.2×10^-4 s^-1 an 80.0 g sample of N2O5 in CCL4 is allowed to decompose at 45°C
a) how long does it take for the quantity of N2O5 to be reduced yo 2.5 g ?
b) how many liters of O2 measured at 745 mmHg and 45°C, are produced up to this point ?
a) The amount of N₂O₅ is lowered to 2.5 g during the course of around 4.41 × 10⁴ seconds or 12.25 hours.
b) 9.71 L of O₂ are generated at 745 mmHg and 45 °C.
How to find quantity?a) To solve for the time required for the quantity of N₂O₅ to be reduced to 2.5 g, use the first-order integrated rate law:
ln[N₂O₅]t/[N₂O₅]0 = -kt
where [N₂O₅]t = concentration of N₂O₅ at time t, [N₂O₅]0 = initial concentration of N₂O₅, k = rate constant, and t = time.
Find the initial concentration of N₂O₅:
n(N₂O₅) = m/M = 80.0 g / 108.01 g/mol = 0.7413 mol
[N₂O₅]0 = n/V = 0.7413 mol / 0.153 L = 4.846 M
where M = molar mass of N₂O₅ and V = volume of the solution.
Substituting the given values into the equation:
ln([N₂O₅]t / 4.846 M) = -6.2×10⁻⁴ s⁻¹ × t
When the quantity of N₂O₅ is reduced to 2.5 g, the concentration is:
n(N₂O₅) = m/M = 2.5 g / 108.01 g/mol = 0.02314 mol
[N₂O₅]t = n/V = 0.02314 mol / 0.153 L = 0.151 M
Substituting this concentration into the equation and solving for t:
ln(0.151 M / 4.846 M) = -6.2×10⁻⁴ s⁻¹ × t
t = 4.41 × 10⁴ s
Therefore, it takes approximately 4.41 × 10⁴ seconds or 12.25 hours for the quantity of N₂O₅ to be reduced to 2.5 g.
b) The balanced equation for the reaction shows that 1 mole of N₂O₅ produces 1/2 mole of O₂:
N₂O₅ → N₂O₄ + 1/2 O2
Therefore, the number of moles of O₂ produced can be calculated using the stoichiometry:
n(O₂) = 1/2 × n(N₂O₅) = 1/2 × 0.7413 mol = 0.3707 mol
The ideal gas law can be used to calculate the volume of O₂ produced at 745 mmHg and 45°C:
PV = nRT
where P = pressure, V = volume, n = number of moles, R = gas constant, and T = temperature in Kelvin.
Convert the pressure to atm and the temperature to Kelvin:
P = 745 mmHg / 760 mmHg/atm = 0.980 atm
T = 45°C + 273.15 = 318.15 K
Substituting the values and solving for V:
V = nRT/P = (0.3707 mol) × (0.08206 L·atm/mol·K) × (318.15 K) / (0.980 atm) = 9.71 L
Therefore, the volume of O₂ produced at 745 mmHg and 45°C is 9.71 L.
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A solution has [H+] = 1.39x10^-6 M. What is the pH?
Answer:
the pH of the solution is approximately 5.857.
Explanation:
The pH of a solution can be calculated using the formula:
pH = -log[H+]
where [H+] is the concentration of hydrogen ions in moles per liter (M).
In this case, [H+] = 1.39x10^-6 M, so:
pH = -log(1.39x10^-6)
= 5.857
Therefore, the pH of the solution is approximately 5.857.
What are four methods of separating mechanical mixture?
Answer: Mixtures can be physically separated by using methods that use differences in physical properties to separate the components of the mixture, such as
evaporation, distillation, filtration and chromatography.Explanation:
If 8.25
mol of C5H12
reacts with excess O2,
how many moles of CO2
will be produced by the following combustion reaction?
C5H12+8O2⟶6H2O+5CO2
The given reaction equation tells us that for every 1 mol of C₅H₁₂, 5 moles of CO₂ will be produced. Since 8.25 mol of C₅H₁₂ is given, 8.25 mol C₅H₁₂ x 5 moles CO₂/1 mol C₅H₁₂ = 41.25 moles CO₂ will be produced.
What is reaction?Reaction is the process of responding to an event or stimulus in a particular way. It can occur at the physical, cognitive, or emotional level. Physically, a reaction could be as simple as a reflex or as complex as a multi-step process. Cognitively, it could involve forming a judgment or understanding. Emotionally, it could involve feelings of fear, shock, anger, or joy. In the context of science, reactions are often chemical or physical processes that involve the conversion of one set of substances into another.
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A compound has the formula X2Fe(CN)6 ∙ 12H2O, where X is an unknown element.
If the compound is 45.34% water by mass, what is the identity of element X?
The identity of element X in the compound X2Fe(CN)6 · 12H2O is sodium (Na).
To find the identity of element X in the compound X2Fe(CN)6 · 12H2O, we can start by determining the molar mass of the compound.
The molar mass of X2Fe(CN)6 is:
2 × molar mass of X + molar mass of Fe + 6 × molar mass of C + 6 × molar mass of N
= 2 × atomic mass of X + atomic mass of Fe + 6 × 12.01 g/mol + 6 × 14.01 g/mol
= 2 × atomic mass of X + 55.85 g/mol + 432.72 g/mol + 84.06 g/mol
= 2 × atomic mass of X + 572.63 g/mol
The molar mass of 12H2O is:
12 × (atomic mass of H + atomic mass of O) = 12 × (1.01 g/mol + 16.00 g/mol) = 216.24 g/mol
The total molar mass of the compound is:
2 × atomic mass of X + 572.63 g/mol + 216.24 g/mol = 2 × atomic mass of X + 788.87 g/mol
Now we can use the given information that the compound is 45.34% water by mass. This means that the mass of water in the compound is 45.34% of the total mass of the compound, and the mass of the rest of the compound (X2Fe(CN)6) is 100% - 45.34% = 54.66% of the total mass of the compound.
Let's assume we have 100 g of the compound. Then the mass of water in the compound is:
45.34 g water = 0.4534 × 100 g compound
The mass of the rest of the compound (X2Fe(CN)6) is:
54.66 g rest of the compound = 0.5466 × 100 g compound
We can now use the mass of the rest of the compound (X2Fe(CN)6) to find the number of moles of the compound:
moles of X2Fe(CN)6 = (54.66 g) / (2 × atomic mass of X + 572.63 g/mol)
We can also use the mass of water to find the number of moles of water:
moles of H2O = (45.34 g) / 18.02 g/mol
Since the compound has 12 moles of water per mole of X2Fe(CN)6, we have:
moles of X2Fe(CN)6 = 1/12 × moles of H2O
We can now set these two expressions for moles of the compound equal to each other and solve for the atomic mass of X:
(54.66 g) / (2 × atomic mass of X + 572.63 g/mol) = 1/12 × (45.34 g) / 18.02 g/mol
Simplifying this equation and solving for the atomic mass of X gives:
atomic mass of X = 22.99 g/mol
The atomic mass of X is very close to the atomic mass of sodium (22.99 g/mol), so it is likely that X is sodium. Therefore, the identity of element X in the compound X2Fe(CN)6 · 12H2O is sodium (Na).
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